Self-assembly of hierarchical MoSx/CNT nanocomposites (2<x<3): towards high performance anode materials for lithium ion batteries

Abstract

Two dimension (2D) layered molybdenum disulfide (MoS2) has emerged as a promising candidate for the anode material in lithium ion batteries (LIBs). Herein, 2D MoSx (2 ≤ x ≤ 3) nanosheet-coated 1D multiwall carbon nanotubes (MWNTs) nanocomposites with hierarchical architecture were synthesized via a high-throughput solvent thermal method under low temperature at 200°C. The unique hierarchical nanostructures with MWNTs backbone and nanosheets of MoSx have significantly promoted the electrode performance in LIBs. Every single MoSx nanosheet interconnect to MWNTs centers with maximized exposed electrochemical active sites, which significantly enhance ion diffusion efficiency and accommodate volume expansion during the electrochemical reaction. A remarkably high specific capacity (i.e., > 1000 mAh/g) was achieved at the current density of 50 mA g−1, which is much higher than theoretical numbers for either MWNTs or MoS2along (~372 and ~670 mAh/g, respectively). We anticipate 2D nanosheets/1D MWNTs nanocomposites will be promising materials in new generation practical LIBs.

Introduction

Advanced energy storage technology is the key to manage the energy supply and demand. Lithium ion batteries (LIBs) have attracted increasing research interests and become one of the main power sources for portable electronic devices and electric vehicles due to its high energy densities, no memory effect and good cycling stability compared to other alternatives1. In commercial LIBs, graphite and lithium metal oxides are commonly employed as the negative (anode) and positive (cathode) electrode materials, respectively. Lithium is the lightest metal that delivers high energy density per electron with a theoretical electrochemical capacity of Li to Li+ is 3860 mAh/g2. However, further advancements in the state-of-the art LIBs are still bottlenecked by the limitation in the anode materials associated with limited capacity (i.e., graphite, ~372 mAh/g), lack of shape flexibility and low ion/electron conductivity3,4. In the past few years, substantial research efforts have been devoted in developing high performance LIBs electrodes. Various carbon nanomaterials, such as one dimension (1D) carbon nanotubes (CNTs)5,6, two dimension (2D) graphene nanosheets7,8, three dimension (3D) graphene foam9,10, have all been investigated as the anode materials in reversible storage of Li+, due to their outstanding electronic conductivities, high charge mobilities and large specific surface areas. As one of the crystalline form of carbon, 1D CNTs has high electric conductivity, good mechanical property, chemical stability and reversible redox reaction capability, which makes it a promising candidate as lithium insertion hosts for LIBs.

The nanostructured multifunctional heterostrucutres have been proved to work synergistically with both high capacity and good cyclability11,12,13,14. Molybdenum disulfide (MoS2), an inorganic graphite analogue, belongs to the layered transition-metal dichalcogenide (LTMDs) family. The weak van der Waals interaction between MoS2 layers allows the Li+ ions to diffuse without a significant increase in volume expansion and prevent the pulverization problem of active materials caused by the repeatly lithiation and delithiation process. The promising potential of MoS2 serving as an anode materials for LIBs is widely reported in the literature due to its attractive specific capacity15,16,17,18,19,20,21. Theoretically the conversion reaction between Li ions and MoS2 leads to four moles of lithium incorporation per mole of MoS2 accounting for 670 mA h g–1 lithium storage capacity that is ~1.8 times higher than the graphite electrode20. With all these significant advantages, MoS2 has attracted lots of research interests and became a promising material as an anode material in LIBs17,18,19. Various methods have been reported for the synthesis of MoS2 including the gas-phase reaction of MoO3 with H2S or S vapor22,23, thermal decomposition of ammonium thiomolybdate24,25 and solvent thermal method26,27.

The solvent thermal process is an important wet chemistry synthesis method and has been widely used to prepare various nanomaterials or nanocomposites. It has been reported CNTs favored the growth of the tubular MoS2 on the surface of carbon nanotube side walls and promoted the formation of tubular MoS2 layers with high crystallinity27,28,29, CNTs/MoS2 composites have also been prepared by the simple solvothermal method30,31. For example, tubular MoS2 layers coating on CNTs were synthesized by the hydrothermal reaction between Na2MoO4 and CS(NH2)2 with the presence of CNTs12. The surface area of MoS2 is limited by the surface area of CNTs. Nevertheless, when aqueous solvent is used, CNTs need to be treated by refluxing in high concentrated strong acid in order to improve the wetting between CNTs and MoS2 precursor28. This acidic treatment will introduce defects in CNTs and negatively affect the electrical properties of CNTs. MoS2/CNTs with a design of 2D MoS2 nanoflakes surrounded by a coating of CNTs was synthesized by using Na2MoO4 and KSCN as reactant and ethylene glycol as solvent in the presence of CNTs27. These composites show higher capacity and improved cycling stability compared to pure MoS2. The MoS2 nanoflakes synthesized are relatively thick and randomly attached to CNTs, which causes a continues capacity fading during cycles27. Wang et al. prepared MoS2 overlayers supported on coaxial CNTs by wet-chemistry process and studied the reversible lithium-storage behaviors of this composite32. A reversible capacity of 400 mAh/g was achieved; however this value is much smaller than the non-coaxial MoS2/CNTs composite.

Results

Herein, we report a unique MoSx/CNTs (2 ≤ x ≤ 3) nanostructure synthesized by simple solvent thermal method at low temperature (200°C) using (NH4)2MoS4 as single reactant and N,N-dimethylformamide (DMF) as solvent in the presence of MWNTs. The synthesized MoSx/MWNTs composites are different from the previous report for MoS2sheath/CNT-core nanoarchitecture32, the MoSx layers are not confined to the MWNTs surface, but extend the layered structure out of the cylindrical tubules (as shown in Figure S1). To understand the forming of hierarchical architecture, the morphology and lattice structure of as prepared MoSx/MWTNs composite was compared with the samples treated under elevated temperature. Figure 1 (A), (B) show the TEM images of MoSx coated MWNTs prepared by the solvent thermal method. The HRTEM in Figure 1 (B), gives a close-up view of the MoSx branch attached on MWNTs surface. The inset shows a fast Fourier transform (FFT) pattern taken from the marked area in Figure 1 (B). The HRTEM and FFT results indicate the semi-crystalline nature of the MoSx layers. As seen in Figure 1 (C) and (D) MoS2sheath/CNT-core nanoarchitecture was obtained by thermal annealing at 800°C under Ar protecting environment. The two layered spacing can be identified to be around ~0.62 and ~0.34 nm, which are in good consistence with the value for MoS2 layers and the lattice spacing between the graphitic planes of MWNTs. Figure 1 (E) and (F) compare the Raman spectra taken from the as obtained MoSx/MWNTs samples and thermal treated MoS2 sheath/CNT-core nanocomposites. The Raman Peaks at around 1347 and 1576 cm−1 belong to MWNTs. The G′ band of MWNTs locates at 2686 cm−1. The Raman Peaks of MoS2 appear at 376 and 402 cm−1. It was also found that the Raman signature of MoS2 dramatically increased after thermal annealing, which suggests the formation of highly crystallized MoS2 layers. This is agreed with the result of HRTEM.

Figure 1
figure1

(A) and (C) Low-magnification TEM image of MoSx/MWNTs with hierarchical nanostructure and MoSx/MWNTs after annealing at 800°C under Ar protection, (B) and (D) HRTEM images of a free standing monolayer MoSxand the side wall of the composite after annealing.

Inset in Figure 1 (B) shows the FFT pattern taken from the marked area. (E) Raman spectra of the MoSx/MWNTs. Figure 1 (F) compares the magnified Raman signature of ta prepared MoSx/MWTNs and the one after annealing.

X-ray photoelectron spectroscopy (XPS) was used to investigate the chemical states of Mo and S in the MoSx/MWNTs nanocomposites. Figure 2 displays the XPS characterization of the samples before and after thermal annealing at 800°C under Ar protecting environment. The high-resolved XPS spectra shows the binding energies of Mo 3d 3/2, Mo 3d 5/2, S 2p ½ and S 2p 3/2 peaks in the thermal annealed MoSx/MWNTs are located at 232.4, 229.2, 163.3 and 162.1 eV, respectively, indicating that Mo4+ existed in the annealed MoSx/MWNTs32. The stoichiometric ratio of S:Mo estimated from the respective integrated peak area of XPS spectra is ~2.125 suggesting the structure is close to MoS2. For the as prepared MoSx/MWNTs two broaden peaks centered at ~232.5 and ~228.9 eV, in addition to the XPS peaks for MoS2 structure, other sets of peaks are also observed. The higher energy shift of Mo 3d3/2 and 3d5/2 doublet are associated with higher valence states. The observation of Mo 3d3/2 and Mo 3d5/2 peaks at 233.6 and 230.5 eV with separation energies close to 3.1 eV can be attributed to the presence of Mo5+ ions33,34. For the non-annealed MoSx/MWNTs the S 2p spectra can be interpreted in terms of two doublets, with S 2p3/2 binding energies of 161.7 and 163.2 eV. Compared to the thermal annealed samples, the additional S 2p1/2 and 2p3/2 energies located at 164.3 and 163.2 eV can be assigned to the binding energies of apical S2− or bridging disulfide S22− ligands. The S 2p spectrum that can be fit with two S 2p doublets, which is similar to those of amorphous MoS335,36. The presence of bridging apical S2− or bridging S22− is in good consistence with the TEM analyses in Figure 1 (B), which reveals that the MoSx obtained are basically semicrystalline. Furthermore, the S/Mo elemental ratio estimated from the integrated peak area of XPS spectra is ~3.0 which also suggests the as grown MoSx is stoichiometrically close to MoS3. The thermal decomposition of (NH4)2MoS4 is accompanied by molybdenum-sulfur redox processes, which include the oxidation of S2− ligands of the MoS42− anion and the reduction of Molybdenum metal from MoVI to MoIV and various thermal decomposition intermediate may exist37. The XPS results confirm the presents of MoS3 while the Raman spectra from the as prepared samples show smaller but visible Raman Peaks of MoS2at 376 and 402 cm−1 (as shown in Figure 1 (E)). Therefore, the exact phase of the MoSx/MWNTs compound is suggested to be a mixture of MoS2 and MoS3.

Figure 2
figure2

Chemical composition analysis by X-Ray photoemission spectroscopy (XPS) for Mo and S.

The lower and upper cures display the corresponding spectrum taken from the as obtained and 800°C annealed MoSx/MWNTs samples respectively.

The growth mechanism of MoSx/MWNTs layered structures were also investigated by varying the Mo/Carbon ratio in the precursor. Figure 3 (A), (B) and (C) show the TEM images of typical MoSx/MWNTs composites prepared with Mo/Carbon ratio of 1:40, 1:20 and 1:10. Figure 3 (D) proposes the growth mechanism of the MoSx/MWNTs composites. With limited amount of MoSx precursor the MoSx forms small segments on the sidewall of MWNTs. The hierarchical structure of MoSx forms and the MoSx layer structure extruding from the sidewall of MWNTs with the increase of Mo/C ratio. For the high concentration precursor, the MoSx layers form uniformly on MWNTs. It has been reported CNTs favored the growth of the tubular MoS2 on the surface of carbon nanotube side walls and promoted the formation of tubular MoS2 layers with high crystallinity27,28, therefore at elevated temperate the MoSx converted to MoS2 and form MoS2sheath/CNT-core nanoarchitecture32.

Figure 3
figure3

(A),(B) and (C) Low-magnification TEM images of MoSx/MWNTs with synthesized with increasing MoSx/MWNTs ratio (1:40, 1:20, 1:10), (D) shows the proposed growth mechanism for forming MoSx/MWNTs hierarchical structure.

Discussion

Compared to the conventional MoS2/MWNTs structure, the novel MoSx/carbon composite has a three dimensional (3D) hierarchical structure, where the 1D multi wall carbon nanotube (MWNTs) as back bones, while the 2D MoSx layers grown on the surface of MWNTs with a partially free standing branch like feature, which provide a large surface area of the active material to accommodate Li+. The hierarchical structure of MoSx/CNTs, could effectively combine the merits of the good electrical conductivity of CNTs and excellent electrochemical performance of individual MoSx layer throughout cycling. Due to the excess of sulphur in MoSx an increased layer distance of S–Mo–S can be expected, which results in less strain and smaller intercalation barrier of Li ions. Meanwhile, the CNTs used in this work have a long tube length, which creates large internal voids in the composites that could absorb and buffer the mechanical stress which caused by the local volume variation during lithium insertion and extraction.

Considering the electrodes with special hierarchical nanocomposites are advantageous to LIBs, we investigate the lithium storage properties of as-prepared MoSx/MWNTs using half-cell configuration. Figure 4 shows the electrochemical performance of MoSx/MWNTs as anode materials. Figure 4 (A) illustrates the first, second, fifth and tenth discharge/charge voltage profiles of the MoSx/MWNTs composite electrode in the voltage range of 0.01 to 3 V (vs. Li/Li+). During the first discharge, the initial discharge capacity between 2.0 to 1.5 V can be attributed in part to the reaction of residual carbon (MWNTs) surface functional group38 and in part to lithium insertion into the MoSx/MWNTs composites forming LinMoSx(0 < n < 4)39, according to the reaction MoSx + nLi+ + ne → LinMoSx27,40. We note that it is previously proposed that a better formulation for MoS3 would be MoV2(S22−)(S2−)4, therefore, the reduction of sulfur during initial discharge can also be considered here39. Following this, the capacity between 1.0 to 0.5 V can be attributed to the conversion reaction process MoSx + 2xLi+ + 2xe → Mo + xLi2S41,42,43. The metal sulfide reacts with lithium ions forming metal nanoparticles and insoluble Li2S matrix20. It was argued that the nanosized metal particles promote the reversible reaction which is responsible for the reversible lithium-storage capacity, therefore the phase segregation of transition metals should be limited in order to improve the cycling stability32. The sloping plateau at the lower voltage region (below 0.5 V) includes the contribution from the formation of a solid electrolyte interface (SEI) and the gel-like polymeric layer on the surface of the active materials44. In the subsequent charge process, a plateau at ~1.3 V and the sloping region above 2.2 V are attributed to the oxidation of Mo particles to MoSx and the oxidation of Li2S to form S, respectively42,45,46. We note that lithium extraction from the LinMoSx phase should also be considered here27,39,40. The initial discharge and charge capacities are found to be 1549 and 1159 mAhg−1, respectively. (with a Coulombic efficiency of 74.8%).The irreversible capacity loss of approximately 25.1% in the 1st cycle can be mainly attributed to the irreversible processes including the electrolyte decomposition and inevitable formation of the SEI, which have been observed for nanosized anode materials47. During the 2nd cycle, the discharge capacity decreases to 1154 mAh/g with a corresponding charge capacity of 1126 mAh/g, leading to a much higher Coulombic efficiency of 97.5%. This value further increased to 99.6% in the 5th cycle and still maintained above 98.6% at the 10th cycle. To further clarify the electrochemical process of the MoSx/MWNTs composite, cyclic voltammograms (CV) measurement of the first three cycles in the voltage range of 3.0 – 0.01 V with a scan rate of 0.1 mVs−1 was shown in Figure 4 (B). In the first cycle a very small reduction peak at ~1.80 V was found, which can be related to the reaction of residual carbon surface functional group38, in part to lithium insertion into the MoSx structure forming LinMoSx39 and the reduction of traced sulfur39. A pronounced reduction peak at ~0.50 V was observed in the first cycle, however for the subsequent cycles, the peak at ~0.50 V disappeared. This process has been attributed to the decomposition of MoSx into Mo nanoparticles embedded in a Li2S matrix through the conversion process42,43. Upon the anodic scan, the oxidation peak at ~1.5 V can be in part attributed to the oxidation of Mo to MoS2 followed by a anodic peak at 2.3 V associated with the oxidation of Li2S into S42,43,45. In addition, lithium extraction from LinMoSx could contribute to these anodic processes depending on the stoichiometry of the LinMoSx39. During the 2nd CV scan, a pair of reduction peak at ~1.3 V and ~1.80 V together with two corresponding oxidation peaks at ~ 1.5 and 2.3 V for the MoSx/MWNTs composite became distinct. The reduction peak at ~1.3 V can be related to the intercalation of Li+ into the MoSx lattice While, the oxidation peaks at ~1.48 V and 2.28 V correspond to the extraction of Li+ from LinMoSx lattice and the oxidation of Li2S, respectively40.

Figure 4
figure4

(A) Voltage profiles of MoSx/MWNTs charged-discharged at 50 mA g−1, (B) Representative cyclic voltammograms of MoSx/MWNTs composite for the first 5 cycles at a scan rate of 0.5 mVs−1 between 0.01 V and 3 V. (C) comparison of cycling stability between MoSx/MWNTs and MWNTs charged-discharged at 50 mA g−1) and (D) Rate capability of MoSx/MWNTs charged and discharged at various current densities.

Figure 4 (C) shows the cycling stability of the MoSx/MWNTs electrode compared to the pristine MWNTs. The specific capacity of the MoSx/MWNTs composite with a Mo/C molar ratio of 1:1 is above 1000 mAh/g which is more than 4 times larger than the pristine MWNTs electrodes under current density of 50 mA/g. The specific capacities of MoSx/MWNTs composites with various Mo/C molar ratios are shown in supporting information Figure S2. Figure 4 (D) shows the rate capability of the MoSx/MWNTs composites at various current densities. The electrode shows the 10th-cycle discharge capacities of 1119, 904, 659, 358 and 197 mAhg−1 at current densities of 50, 200, 500, 1000 and 2000 mAg−1, respectively. Even at a very high current density of 1000 mAg−1, the composite electrode can still deliver a capacity of 358 mAhg−1, which is comparable with the theoretical capacity of graphite (372 mAh g−1). Furthermore, after the current density returns from 2000 mAg−1 to 50 mAg−1, the specific capacity of MoSx/MWNTs electrode can recover to 1087 mAhg−1 and remain 1098 mAhg−1 after 10 cycles. Our MoSx/CNTs have shown a remarkably high reversible specific capacity (i.e., > 1000 mAh/g) at the current density of 50 mA g−1, which is much larger than the “theoretical” capacity value of MoS2 (670 mAh/g assuming 4 lithium ions per MoS2) and CNTs along. We note that specific capacity of MoS2 higher than 670 mAh/g is well-documented in the literature45,48,15. It was shown that MoS2 can take up to 8 lithium ions with major capacity between 0.01 to 1.0 V vs. Li/Li+ 15, which corresponds to a theoretical capacity up to 1334 mAh/g. It is believed that the lithium ions can be stored in different defect sites of the MoS2 depending on the morphology of the material15. In addition, Kartick et al. reported that MoS2/CNT composites prepared by dry grinding method can achieve a reversible storage capacity around 1000 mAh/g49 and X. Cao et al. reported that the MoS2 layers grown on CVD-G has a reversible capacity above 1000 mAh/g50. We believe that the high capacity observed in our study is associated with the unique material structure and defect distribution of MoSx/CNT. It worth mentioning that the MoSx/MWNTs composites had better rate performance compared to the reported single-layer MoS2-graphene composites40 and much improved cycling stability than the MoS2 electrodes27,40. As demonstrated by the schematical illustration image in Figure 5, the high rate capability can be attributed to the unique hierarchical nanoarchitecture of MoSx/MWNTs which provide structural stability and transport advantages for both electrons and lithium ions. The Li+ ion from the surrounding of MoSx/MWNTs have sufficient contact with the Li accommodate layers and the exposed MoSx edges provides abundant intercalations tunnels. The MWNTs provide fast electronic conduction channels and ensure the individual high specific MoSx layerelectrically connected during charge/discharge cycles, meanwhile the Li+ are accommodated in the metal sulfide layers.

Figure 5
figure5

Schematic illustration of the diffusion of electron and Li.

The Li ion can diffuse into the hierarchical MoSX/MWNTs nanocomposites easily from the open space between neighboring. Hierarchical structures enhance the contact area, shorten the Li ion diffusion length in the nanosheets and ensure that Li and electron diffuse with little resistance.

In conclusion, the outstanding performance of hierarchical composites based anode material is attributable to the unique synergy at the nanoscale between 1D CNT and Li+ hosting 2D nanoseets. The CNTs provide high conductance channels and ensure the individual high specific MoSxlayerelectrically connected during charge/discharge cycles, meanwhile the Li+ are accommodated in the metal sulfide layers. Moreover, the designed hierarchical structure with maximized surface and increased layer distance of S–Mo–S have resulted in less strain and smaller intercalation barrier of Li ions, which maintain the high lithium storage in reversible capacities, stable cycling lifetime and excellent rate performances. Other promising applications are also anticipated to arise that take advantage of the abundant active MoSx edges as catalysts51,52,53,54.

Methods

Preparation of MoSx/MWNTs nanocomposite

The multi-walled carbon nanotubes (MWNTs), L-MWNTs-60100, were purchased from Shen-zhen Nanotech Port Co., Ltd, Shenzhen, China. The (NH4)2MoS4 powder and N,N-dimethylformamide (DMF) were purchased from Sigma-Aldrich. All chemicals and raw materials were directly used without further purification. The MWNTs/MoS2 hybrid was prepared by a solvent thermal process. In a typical experiment, 220 mg (NH4)2MoS4 powder (Sigma-Aldrich) and 100 mg MWNTs were mixed and dispersed into 30 ml of N,N-dimethylformamide (DMF) in a 40 ml Teflon autoclave. After that, the solution was sonicated at room temperature for approximately 10 mins until homogeneous solution was achieved. Then the autoclave was sealed tightly and heated at 200°C for 10 hours under autogenous pressure without intentional control of ramping and cooling rate. After cooled down to room temperature, the product was extracted by centrifugation at 10,000 rpm for 5 min. To remove the unreacted molecules and most of the DMF residuals the product was dispersed in DI water and recollected by centrifugation, this washing step was repeated for at least 5 times, the final products was MWNTs/MoSx nano composite.

Materials characterization

X-ray photoelectron spectroscopy (XPS) analysis was performed on a KRATOS AXIS ULTRA-DLD spectrometer with a monochromatic Al Kα1 radiation (hv = 1486.6 eV). The morphologies and microstructures of the products were characterized by transmission electron microscopy (TEM) and high resolution TEM (HRTEM) on a JEM 2100F microscope. The Raman spectra were obtained by using WITec CRM 200 confocal Raman microscopy system with a laser wavelength of 488 nm and spot size of 0.5 μm. To calibrate the wavenumber, the Si peak at 520 cm−1 was used as a reference.

Electrochemical measurements

The electrochemical performance of MWNTs/MoSx nanocomposites electrode was measured with a half-cell lithium ion battery (LIBs) configuration. The 2032 coin-type cells were assembled in an argon-filled glove-box with both of the moisture and oxygen level less than 1 ppm. The working electrode material slurry were prepared by mixing MWNTs/MoSx, carbon black and poly(vinyldifluoride) (PVDF) at a weight ratio of 80:10:10, several drops of N-methylpyrrolidone (NMP) solvent was added into the mixture to prepare the active materials slurry. The resulting slurry was then uniformly pasted onto Ni foam, with mass loading of 4 ~ 6 mg. Lithium sheet was used as anodes and 1 M LiPF6 in a 1/1 (volume ratio) mixture of ethylene carbonate (EC)/dimethyl carbonate (DMC) as electrolyte. Cegard® 2400 was used as the separator of the battery. The cells were tested on a NEWARE multi-channel battery test system with galvanostatic charge and discharge in the voltage range between 0.01 and 3.0 V vs. Li/Li+ at various current density at room temperature. The cyclic Voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were tested on an electrochemical workstation (VMP3, Bio-Logic).

References

  1. Armand, M. & Tarascon, J. M. Building better batteries. Nature 451, 652–657 (2008).

    CAS  ADS  Article  Google Scholar 

  2. Cheng, F., Tao, Z., Liang, J. & Chen, J. Template-Directed Materials for Rechargeable Lithium-Ion Batteries†. Chem Mater 20, 667–681 (2007).

    Article  CAS  Google Scholar 

  3. Tarascon, J. M. & Armand, M. Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001).

    CAS  ADS  Article  Google Scholar 

  4. Etacheri, V., Marom, R., Elazari, R., Salitra, G. & Aurbach, D. Challenges in the development of advanced Li-ion batteries: a review. Energy & Environmental Science 4, 3243–3262 (2011).

    CAS  Article  Google Scholar 

  5. Wang, K. et al. Super-Aligned Carbon Nanotube Films as Current Collectors for Lightweight and Flexible Lithium Ion Batteries. Adv Funct Mater 23, 846–853 (2013).

    CAS  Article  Google Scholar 

  6. Venkatachalam, S. et al. In-Situ Formation of Sandwiched Structures of Nanotube/CuxOy/Cu Composites for Lithium Battery Applications. ACS Nano 3, 2177–2184 (2009).

    CAS  MathSciNet  Article  Google Scholar 

  7. Wu, Z.-S. et al. Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance. ACS Nano 4, 3187–3194 (2010).

    CAS  PubMed  Article  Google Scholar 

  8. Zhu, X., Zhu, Y., Murali, S., Stoller, M. D. & Ruoff, R. S. Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries. ACS Nano 5, 3333–3338 (2011).

    CAS  PubMed  Article  Google Scholar 

  9. Zhang, W. et al. A facile approach to nanoarchitectured three-dimensional graphene-based Li–Mn–O composite as high-power cathodes for Li-ion batteries. Beilstein Journal of Nanotechnology 3, 513–523 (2012).

    PubMed  PubMed Central  Article  CAS  Google Scholar 

  10. Ji, H. et al. Ultrathin Graphite Foam: A Three-Dimensional Conductive Network for Battery Electrodes. Nano Lett 12, 2446–2451 (2012).

    CAS  ADS  PubMed  Article  Google Scholar 

  11. Zhu, G.-N. et al. Binary Li4Ti5O12-Li2Ti3O7 Nanocomposite as an Anode Material for Li-Ion Batteries. Adv Funct Mater 23, 640–647 (2013).

    CAS  Article  Google Scholar 

  12. Liang, J., Zhao, Y., Guo, L. & Li, L. Flexible Free-Standing Graphene/SnO2 Nanocomposites Paper for Li-Ion Battery. Acs Appl Mater Interfaces 4, 5742–5748 (2012).

    CAS  PubMed  Article  Google Scholar 

  13. Hassoun, J., Lee, K.-S., Sun, Y.-K. & Scrosati, B. An Advanced Lithium Ion Battery Based on High Performance Electrode Materials. J Am Chem Soc 133, 3139–3143 (2011).

    CAS  PubMed  Article  Google Scholar 

  14. Hosono, E., Kudo, T., Honma, I., Matsuda, H. & Zhou, H. Synthesis of Single Crystalline Spinel LiMn2O4 Nanowires for a Lithium Ion Battery with High Power Density. Nano Lett 9, 1045–1051 (2009).

    CAS  ADS  PubMed  Article  Google Scholar 

  15. Feng, C. et al. Synthesis of molybdenum disulfide (MoS2) for lithium ion battery applications. Mater Res Bull 44, 1811–1815 (2009).

    CAS  Article  Google Scholar 

  16. Xiao, J. et al. Exfoliated MoS2 Nanocomposite as an Anode Material for Lithium Ion Batteries. Chem Mater 22, 4522–4524 (2010).

    CAS  Article  Google Scholar 

  17. Chang, K. & Chen, W. l-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries. ACS Nano 5, 4720–4728 (2011).

    CAS  PubMed  Article  Google Scholar 

  18. Hwang, H., Kim, H. & Cho, J. MoS2 Nanoplates Consisting of Disordered Graphene-like Layers for High Rate Lithium Battery Anode Materials. Nano Lett 11, 4826–4830 (2011).

    CAS  ADS  PubMed  Article  Google Scholar 

  19. Zhang, C., Wang, Z., Guo, Z. & Lou, X. W. Synthesis of MoS2–C One-Dimensional Nanostructures with Improved Lithium Storage Properties. Acs Appl Mater Interfaces 4, 3765–3768 (2012).

    CAS  PubMed  Article  Google Scholar 

  20. Sen, U. K. & Mitra, S. High-Rate and High-Energy-Density Lithium-Ion Battery Anode Containing 2D MoS2 Nanowall and Cellulose Binder. Acs Appl Mater Interfaces 5, 1240–1247 (2013).

    CAS  PubMed  Article  Google Scholar 

  21. Wang, M., Li, G., Xu, H., Qian, Y. & Yang, J. Enhanced Lithium Storage Performances of Hierarchical Hollow MoS2 Nanoparticles Assembled from Nanosheets. Acs Appl Mater Interfaces 5, 1003–1008 (2013).

    CAS  PubMed  Article  Google Scholar 

  22. Lin, Y.-C. et al. Wafer-scale MoS2 thin layers prepared by MoO3 sulfurization. Nanoscale 4, 6637–6641 (2012).

    CAS  ADS  Article  Google Scholar 

  23. Zhan, Y., Liu, Z., Najmaei, S., Ajayan, P. M. & Lou, J. Large-Area Vapor-Phase Growth and Characterization of MoS2 Atomic Layers on a SiO2 Substrate. Small 8, 966–971 (2012).

    CAS  Article  Google Scholar 

  24. Shi, Y. et al. van der Waals Epitaxy of MoS2 Layers Using Graphene As Growth Templates. Nano Lett 12, 2784–2791 (2012).

    CAS  ADS  PubMed  Article  Google Scholar 

  25. Liu, K. K. et al. Growth of Large-Area and Highly Crystalline MoS2 Thin Layers on Insulating Substrates. Nano Letters 12, 1538–1544 (2012).

    CAS  ADS  PubMed  Article  PubMed Central  Google Scholar 

  26. Zhou, W. et al. Synthesis of Few-Layer MoS2 Nanosheet-Coated TiO2 Nanobelt Heterostructures for Enhanced Photocatalytic Activities. Small 9, 140–147 (2013).

    CAS  Article  Google Scholar 

  27. Wang, S. et al. Solvothermal Synthesis of MoS2/Carbon Nanotube Composites with Improved Electrochemical Performance for Lithium Ion Batteries. Nanoscience and Nanotechnology Letters 4, 378–383 (2012).

    CAS  Article  Google Scholar 

  28. Ma, L., Chen, W. X., Xu, Z. D., Xia, J. B. & Li, X. Carbon nanotubes coated with tubular MoS2 layers prepared by hydrothermal reaction. Nanotechnology 17, 571–574 (2006).

    CAS  ADS  Article  Google Scholar 

  29. Koroteev, V. O. et al. Charge Transfer in the MoS2/Carbon Nanotube Composite. The Journal of Physical Chemistry C 115, 21199–21204 (2011).

    CAS  Article  Google Scholar 

  30. Ma, L., Chen, W.-X., Xu, Z.-D., Xia, J.-B. & Li, X. Carbon nanotubes coated with tubular MoS 2 layers prepared by hydrothermal reaction. Nanotechnology 17, 571 (2006).

    CAS  ADS  Article  Google Scholar 

  31. Song, X. C., Zheng, Y. F., Zhao, Y. & Yin, H. Y. Hydrothermal synthesis and characterization of CNT@MoS2 nanotubes. Mater Lett 60, 2346–2348 (2006).

    CAS  Article  Google Scholar 

  32. Wang, Q. & Li, J. Facilitated Lithium Storage in MoS2 Overlayers Supported on Coaxial Carbon Nanotubes. The Journal of Physical Chemistry C 111, 1675–1682 (2007).

    CAS  Article  Google Scholar 

  33. Baker, M. A., Gilmore, R., Lenardi, C. & Gissler, W. XPS investigation of preferential sputtering of S from MoS2 and determination of MoSx stoichiometry from Mo and S peak positions. Appl Surf Sci 150, 255–262.

  34. Wang, H. W., Skeldon, P. & Thompson, G. E. XPS studies of MoS2 formation from ammonium tetrathiomolybdate solutions. Surface and Coatings Technology 91, 200–207 (1997).

    CAS  Article  Google Scholar 

  35. Merki, D., Fierro, S., Vrubel, H. & Hu, X. Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water. Chemical Science 2, 1262–1267 (2011).

    CAS  Article  Google Scholar 

  36. Chang, Y.-H. et al. Highly Efficient Electrocatalytic Hydrogen Production by MoSx Grown on Graphene-Protected 3D Ni Foams. Adv Mater 25, 756–760 (2013).

    CAS  PubMed  Article  Google Scholar 

  37. Weber, T., Muijsers, J. C. & Niemantsverdriet, J. W. Structure of Amorphous MoS3. J Phys Chem 99, 9194–9200 (1995).

    CAS  Article  Google Scholar 

  38. Chang, K. & Chen, W. Single-layer MoS2/graphene dispersed in amorphous carbon: towards high electrochemical performances in rechargeable lithium ion batteries. J Mater Chem 21, 17175–17184 (2011).

    CAS  Article  Google Scholar 

  39. Scott, R. A. et al. Reactions of molybdenum trisulfide, tungsten trisulfide, tungsten triselenide and niobium triselenide with lithium. Metal cluster rearrangement revealed by EXAFS. Inorg Chem 25, 1461–1466 (1986).

    CAS  Article  Google Scholar 

  40. Wang, Z. et al. CTAB-assisted synthesis of single-layer MoS2-graphene composites as anode materials of Li-ion batteries. Journal of Materials Chemistry A 1, 2202–2210 (2013).

    Article  Google Scholar 

  41. Wang, G. X., Bewlay, S., Yao, J., Liu, H. K. & Dou, S. X. Tungsten disulfide nanotubes for lithium storage. Electrochem. Solid State Lett. 7, A321–A323 (2004).

    CAS  Article  Google Scholar 

  42. Yang, L. et al. Hierarchical MoS2/Polyaniline Nanowires with Excellent Electrochemical Performance for Lithium-Ion Batteries. Adv Mater 25, 1180–1184 (2013).

    CAS  PubMed  Article  Google Scholar 

  43. Fang, X. et al. Lithium storage performance in ordered mesoporous MoS2 electrode material. Micropor Mesopor Mater 151, 418–423 (2012).

    CAS  Article  Google Scholar 

  44. Chang, K. & Chen, W. X. L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries. ACS Nano 5, 4720–4728 (2011).

    CAS  PubMed  Article  Google Scholar 

  45. Xiao, J. et al. Electrochemically Induced High Capacity Displacement Reaction of PEO/MoS2/Graphene Nanocomposites with Lithium. Adv Funct Mater 21, 2840–2846 (2011).

    CAS  Article  Google Scholar 

  46. Fang, X. et al. Mechanism of Lithium Storage in MoS2 and the Feasibility of Using Li2S/Mo Nanocomposites as Cathode Materials for Lithium–Sulfur Batteries. Chemistry – An Asian Journal 7, 1013–1017 (2012).

    CAS  Article  Google Scholar 

  47. Owejan, J. E., Owejan, J. P., DeCaluwe, S. C. & Dura, J. A. Solid Electrolyte Interphase in Li-Ion Batteries: Evolving Structures Measured In situ by Neutron Reflectometry. Chem Mater 24, 2133–2140 (2012).

    CAS  Article  Google Scholar 

  48. Chang, K. & Chen, W. In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries. Chem Commun 47, 4252–4254 (2011).

    CAS  Article  Google Scholar 

  49. Bindumadhavan, K., Srivastava, S. K. & Mahanty, S. MoS2-MWCNT hybrids as a superior anode in lithium-ion batteries. Chem Commun 49, 1823–1825 (2013).

    CAS  Article  Google Scholar 

  50. Cao, X. et al. Preparation of MoS2-Coated Three-Dimensional Graphene Networks for High-Performance Anode Material in Lithium-Ion Batteries. Small, 10.1002/smll.201202697 (2013).

  51. Kibsgaard, J. et al. Cluster−Support Interactions and Morphology of MoS2 Nanoclusters in a Graphite-Supported Hydrotreating Model Catalyst. J Am Chem Soc 128, 13950–13958 (2006).

    CAS  PubMed  Article  Google Scholar 

  52. Laursen, A. B., Kegnaes, S., Dahl, S. & Chorkendorff, I. Molybdenum sulfides-efficient and viable materials for electro - and photoelectrocatalytic hydrogen evolution. Energy & Environmental Science 5, 5577–5591 (2012).

    CAS  Article  Google Scholar 

  53. Bian, X. et al. Nanocomposite of MoS2 on ordered mesoporous carbon nanospheres: A highly active catalyst for electrochemical hydrogen evolution. Electrochem Commun 22, 128–132 (2012).

    CAS  Article  Google Scholar 

  54. Li, Y. et al. MoS2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction. J Am Chem Soc 133, 7296–7299 (2011).

    CAS  PubMed  Article  Google Scholar 

Download references

Acknowledgements

This work is supported by SMART innovation grant and SUTD-ZJU research grant ZJURP1100104.

Author information

Affiliations

Authors

Contributions

Y.S. and H.Y.Y. conceived the project. Y.S., Y.W. and H.Y.Y. designed and carried out research, analyzed data. Y.S. and H.Y.Y. wrote the paper. A.Y.S.T., J.I.W. and C.L.H. contributed in material characterization and discussion. Y.C.L. and L.J.L. provide scientific advice. All authors contributed to the writing and editing.

Ethics declarations

Competing interests

The authors declare no competing financial interests.

Electronic supplementary material

Rights and permissions

This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by/3.0/

Reprints and Permissions

About this article

Cite this article

Shi, Y., Wang, Y., Wong, J. et al. Self-assembly of hierarchical MoSx/CNT nanocomposites (2<x<3): towards high performance anode materials for lithium ion batteries. Sci Rep 3, 2169 (2013). https://doi.org/10.1038/srep02169

Download citation

Further reading

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.