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Molecular cages

Unlocking the geometry of bonding

A high-symmetry tetrahedral cage made using smaller tripodal cages at its four vertices shows a high surface area for CO2 and SF6 adsorption.

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Fig. 1: The development of high-symmetry molecular structures.

References

  1. Tahara, K., Fujita, T., Sonoda, M., Shiro, M. & Tobe, Y. J. Am. Chem. Soc. 130, 14339–14345 (2008).

    Article  CAS  PubMed  Google Scholar 

  2. Stang, P. J., Cao, D. H., Saito, S. & Arif, A. M. J. Am. Chem. Soc. 117, 6273–6283 (1995).

    Article  CAS  Google Scholar 

  3. Chichak, K. S. et al. Science 304, 1308–1312 (2004).

    Article  CAS  PubMed  Google Scholar 

  4. Furukawa, H., Cordova, K. E., O’Keeffe, M. & Yaghi, O. M. Science 341, 1230444 (2013).

    Article  PubMed  Google Scholar 

  5. Rowan, S. J., Cantrill, S. J., Cousins, G. R. L., Sanders, J. K. M. & Stoddart, J. F. Angew. Chem. Int. Ed. 41, 898–952 (2002).

    Article  Google Scholar 

  6. Pitarch, M., McKee, V., Nieuwenhuyzen, M. & McKervey, M. A. J. Org. Chem. 63, 946–951 (1998).

    Article  CAS  Google Scholar 

  7. Zhu, Q. et al. Nat. Synth. https://doi.org/10.1038/s44160-024-00531-7 (2024).

    Article  Google Scholar 

  8. Blotny, G. Tetrahedron 62, 9507–9522 (2006).

    Article  CAS  Google Scholar 

  9. Wang, D.-X. et al. Chem. Eur. J. 16, 13053–13057 (2010).

    Article  CAS  PubMed  Google Scholar 

  10. Benke, B. P., Kirschbaum, T., Graf, J., Gross, J. H. & Mastalerz, M. Nat. Chem. 15, 413–423 (2023).

    Article  CAS  PubMed  Google Scholar 

Download references

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Correspondence to Chenfeng Ke.

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Li, F., Ke, C. Unlocking the geometry of bonding. Nat. Synth (2024). https://doi.org/10.1038/s44160-024-00539-z

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