A high-symmetry tetrahedral cage made using smaller tripodal cages at its four vertices shows a high surface area for CO2 and SF6 adsorption.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Tahara, K., Fujita, T., Sonoda, M., Shiro, M. & Tobe, Y. J. Am. Chem. Soc. 130, 14339–14345 (2008).
Stang, P. J., Cao, D. H., Saito, S. & Arif, A. M. J. Am. Chem. Soc. 117, 6273–6283 (1995).
Chichak, K. S. et al. Science 304, 1308–1312 (2004).
Furukawa, H., Cordova, K. E., O’Keeffe, M. & Yaghi, O. M. Science 341, 1230444 (2013).
Rowan, S. J., Cantrill, S. J., Cousins, G. R. L., Sanders, J. K. M. & Stoddart, J. F. Angew. Chem. Int. Ed. 41, 898–952 (2002).
Pitarch, M., McKee, V., Nieuwenhuyzen, M. & McKervey, M. A. J. Org. Chem. 63, 946–951 (1998).
Zhu, Q. et al. Nat. Synth. https://doi.org/10.1038/s44160-024-00531-7 (2024).
Blotny, G. Tetrahedron 62, 9507–9522 (2006).
Wang, D.-X. et al. Chem. Eur. J. 16, 13053–13057 (2010).
Benke, B. P., Kirschbaum, T., Graf, J., Gross, J. H. & Mastalerz, M. Nat. Chem. 15, 413–423 (2023).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Rights and permissions
About this article
Cite this article
Li, F., Ke, C. Unlocking the geometry of bonding. Nat. Synth (2024). https://doi.org/10.1038/s44160-024-00539-z
Published:
DOI: https://doi.org/10.1038/s44160-024-00539-z