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Electrocatalysis

Engineering the catalyst microenvironment

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A heterogeneous catalyst adlayer for CO2 reduction is reported which suppresses H2 evolution and promotes multicarbon product formation in strong acid. The resulting electrolyser has a single-pass CO2 conversion efficiency of 45%.

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Fig. 1: Adlayer–catalyst interface design for electrochemical reduction of CO2 in acidic media.

References

  1. Dihn, C.-T., Li, Y. C. & Sargent, E. H. Joule 3, 13–15 (2019).

    Article  Google Scholar 

  2. Liu, M. et al. Nature 537, 382–386 (2016).

    Article  CAS  PubMed  Google Scholar 

  3. Huang, J. E. et al. Science 372, 1074–1078 (2021).

    Article  CAS  PubMed  Google Scholar 

  4. Zhao, Y. et al. Nat. Synth. https://doi.org/10.1038/s44160-022-00234-x (2023).

    Article  Google Scholar 

  5. Garg, S. et al. J. Mater. Chem. A 8, 1511–1544 (2020).

    Article  CAS  Google Scholar 

  6. Bui, J. C. et al. Acc. Chem. Res. 55, 484–494 (2022).

    Article  CAS  PubMed  Google Scholar 

  7. Kim, C. et al. Nat. Energy 6, 1026–1034 (2021).

    Article  CAS  Google Scholar 

  8. Li, X. et al. Matter 3, 1507–1540 (2020).

    Article  Google Scholar 

  9. Schmidt, O. et al. Int. J. Hydr. Energy 42, 30470–30492 (2017).

    Article  CAS  Google Scholar 

  10. Liu, W. et al. Nat. Commun. 13, 1877 (2022).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

Download references

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Correspondence to Anna Klinkova.

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The authors declare no completing interests.

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Medvedev, J., Klinkova, A. Engineering the catalyst microenvironment. Nat. Synth 2, 389–390 (2023). https://doi.org/10.1038/s44160-023-00274-x

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