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References
Robatjazi, H. et al. Plasmon-driven carbon–fluorine (C(sp3)–F bond activation with mechanistic insights into hot-carrier-mediated pathways. Nat. Catal. 3, 564–573 (2020).
Sivan, Y., Baraban, J., Un, I. W. & Dubi, Y. Comment on ‘quantifying hot carrier and thermal contributions in plasmonic photocatalysis’. Science 364, eaaw9367 (2019).
Sivan, Y., Baraban, J. & Dubi, Y. Experimental practices required to isolate thermal effects in plasmonic photo-catalysis—lessons from recent experiments. OSA Continuum 3, 483–497 (2020).
Zhou, L. et al. Quantifying hot carrier and thermal contributions in plasmonic photocatalysis. Science 362, 69–72 (2018).
Sivan, Y., Un, I. W. & Dubi, Y. Thermal effects—an alternative mechanism for plasmonic-assisted photo-catalysis. Chem. Sci. 11, 5017–5027 (2020).
Mukherjee, S. et al. Hot electrons do the impossible: plasmon-induced dissociation of H2 on Au. Nano Lett. 13, 240–247 (2013).
Seemala, B. et al. Plasmon-mediated catalytic O2 dissociation on Ag nanostructures: hot electrons or near fields? ACS Energy Lett. 4, 1803–1809 (2019).
Baffou, G., Bordacchini, I., Baldi, A. & Quidant, R. Simple experimental procedures to distinguish photothermal processes in plasmon-driven chemistry. Light Sci. Appl. 9, 108 (2020).
Zhang, X. et al. Plasmon-enhanced catalysis: distinguishing thermal and nonthermal effects. Nano Lett. 18, 1714–1723 (2018).
Li, X., Zhang, X., Everitt, H. O. & Liu, J. Light-induced thermal gradients in Ruthenium catalysts significantly enhance ammonia production. Nano Lett. 19, 1706–1711 (2019).
Un, I. W., Dubi, Y. & Sivan, Y. The photothermal nonlinearity in plasmon-assisted photo-catalysis. Nanoscale https://doi.org/10.1039/D1NR07822D (2022).
Un, I. W. & Sivan, Y. Parametric study of temperature distribution in plasmon-assisted photocatalysis. Nanoscale 12, 17821–17832 (2020).
Li, H., Rivallan, M., Thibault-Starzyk, F., Traverta, A. & Meunier, F. C. Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies. Phys. Chem. Chem. Phys. 15, 7321–7327 (2013).
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Nature Catalysis thanks Jacinto Sa and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
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Dubi, Y., Un, I.W., Baraban, J.H. et al. Distinguishing thermal from non-thermal contributions to plasmonic hydrodefluorination. Nat Catal 5, 244–246 (2022). https://doi.org/10.1038/s41929-022-00767-6
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DOI: https://doi.org/10.1038/s41929-022-00767-6
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