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HOMOGENEOUS CARBON DIOXIDE REDUCTION

Harmonious hydrogenation catalysts

Development of an earth-abundant and inexpensive copper-based catalyst is desirable for CO2 hydrogenation. Now, the combined application of a stable copper hydride and a Lewis pair is shown to effect activation of CO2 as well as heterolysis of H2, achieving significant turnover numbers.

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Fig. 1: Catalytic CO2 hydrogenation.

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Correspondence to Yoshihito Kayaki.

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Kayaki, Y., Watari, R. Harmonious hydrogenation catalysts. Nat Catal 1, 739–740 (2018). https://doi.org/10.1038/s41929-018-0163-9

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