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Biaxial strain tuning of the optical properties of single-layer transition metal dichalcogenides

  • npj 2D Materials and Applicationsvolume 1, Article number: 10 (2017)
  • doi:10.1038/s41699-017-0013-7
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Since their discovery, single-layer semiconducting transition metal dichalcogenides have attracted much attention, thanks to their outstanding optical and mechanical properties. Strain engineering in these two-dimensional materials aims to tune their bandgap energy and to modify their optoelectronic properties by the application of external strain. In this paper, we demonstrate that biaxial strain, both tensile and compressive, can be applied and released in a timescale of a few seconds in a reproducible way on transition metal dichalcogenides monolayers deposited on polymeric substrates. We can control the amount of biaxial strain applied by letting the substrate expand or compress. To do this, we change the substrate temperature and choose materials with a large thermal expansion coefficient. After the investigation of the substrate-dependent strain transfer, we performed micro-differential spectroscopy of four transition metal dichalcogenides monolayers (MoS2, MoSe2, WS2, WSe2) under the application of biaxial strain and measured their optical properties. For tensile strain, we observe a redshift of the bandgap that reaches a value as large as 95 meV/% in the case of single-layer WS2 deposited on polypropylene. The observed bandgap shifts as a function of substrate extension/compression follow the order MoSe2 < MoS2 < WSe2 < WS2. Theoretical calculations of these four materials under biaxial strain predict the same trend for the material-dependent rates of the shift and reproduce well the features observed in the measured reflectance spectra.


Strain engineering has been proposed as a prospective route to modify the electronic and optical properties of two-dimensional (2D) materials.1,2,3,4 The interest in this topic is motivated by their resilience to mechanical deformations. These systems stand deformations of the order of 10%,5, 6 while conventional 3D semiconductors break at quite moderate deformations of 0.5–1.5%.7 Apart from the mechanical toughness, another key question of strain engineering of 2D materials is how they can be conveniently and reproducibly strained. While 3D systems are typically stressed by epitaxially growing them onto substrates with a certain lattice parameter mismatch, strain in 2D systems can be applied more directly by folding,8 stretching9,10,11,12,13,14 and bending.15,16,17,18,19,20,21,22,23,24,25 Moreover, strain in 2D materials can be easily varied continuously in time, helping to achieve a modulation of the electronic properties. Experiments on MoS2 single-layer and few-layer flakes have already demonstrated that the optical band gap is tunable by 50 meV/% for uniaxial strain15, 16 and 100 meV/% for biaxial strain.14 These results open the door to fabricate devices whose optical and electronic properties can be externally controlled by the application of strain.26

Most of the strain engineering experiments to date have been mainly focused on uniaxial strain under static conditions. However, time-dependent straining is desirable for many applications, such as sensors, optical modulators or active optic devices. Here, we explore the use of biaxial strain to modulate the reflectivity of single layer transition metal dichalcogenides (TMDCs) on a timescale of a few seconds. We investigate the strain transfer from thermally expanded or compressed polydimethylsiloxane (PDMS) substrate to a MoS2 monolayer. PDMS is a polymer commonly used in strain engineering experiments with 2D materials. However, we find that this substrate is not efficient in compressing or extending the 2D material on top. Switching to polypropylene (PP) substrates we find that biaxial strain can be applied reproducibly without slippage up to a maximum tensile biaxial strain of 1%. We investigate the effects of strain on the optical properties of single-layers MoS2, MoSe2, WS2 and WSe2. To our knowledge, this is the first experimental investigation of MoSe2, WS2 and WSe2 under the application of biaxial strain. For increasing tensile strain, a redshift of the optical band gap of these 2D TMDCs is observed, which reaches, in the case of WS2, the large value of 95 meV for a substrate strain of only 1%. The observed bandgap shifts as a function of substrate extension/compression follow the order MoSe2 < MoS2 < WSe2 < WS2, i.e., with WS2 providing the largest bandgap tunability and MoSe2 the lowest. Using the thermal expansion mismatch between a 2D material and a substrate is a simple but powerful way to achieve biaxial expansion or compression of the 2D material, which is technically more difficult to achieve than uniaxial strain. This method can be readily applied to other 2D materials and be used to vary the strain in real time.

In order to apply biaxial strain to single-layer TMDCs, we changed the temperature of the substrate with a Peltier heater/cooler and exploit the large mismatch between the thermal expansion coefficients of the substrate and the TMDC flake deposited on top, similarly to previous work by part of the authors.12 In this work, however, it was not possible to directly determine the substrate expansion and the biaxial strain was limited only to tensile strain. The selected substrate could not effectively transfer the strain to the 2D layer because of its low Young’s modulus and only static strain was studied.11, 27 Here, we present a simple method to accurately calibrate the substrate expansion and we extend the straining method also to compressive strain. By analysing the nature of the strain transfer mechanism, we find a substrate that optimises it and we study time-dependent strain.


Figure 1a shows a sketch of the thermal expansion calibration method. In the calibration procedure, we measure the distance between periodical features, patterned on the surface of the polymeric substrate by recording optical images of the substrate while changing the temperature with a Peltier element (10–110 °C). Figure 1b displays two fragments of optical images of a PDMS substrate with periodic holes (diameter 3 μm and pitch 4 μm) taken at a temperature of 30 °C and 110 °C. Thanks to the presence of the array of holes the thermal expansion of the PDMS substrate is readily visualised when comparing the two images.

Fig. 1
Fig. 1

a Schematic of the temperature-dependent experiment. Substrate heating (cooling) causes the thermal expansion (contraction) of the substrate that induces biaxial strain on the flake pre-deposited on top. Control over the temperature is achieved with a Peltier heating/cooling element. b Optical microscope image (in grey scale) of a PDMS substrate with periodic holes taken at two different temperatures (30 and 110 °C). Notice the expanded substrate at higher temperature. c Average percentage increase of the distance between holes as a function of temperature. The dashed line is a linear fit to the data. The slope yields the expansion coefficient of PDMS

We analyse the spacing between holes at different temperatures by studying the autocorrelation function of the intensity of the images, which provides a powerful tool to extract periodical features as explained in Supplementary Information Section S1. For each temperature T, we extract the distance L(T) between adjacent holes. The change in distance between holes ΔL is related to the change in temperature T according to:

L T - L T = 2 5 C L T = 2 5 C = Δ L L = α Sub T - 2 5 C ,

where αSub is the thermal expansion coefficient of the material. Figure 1c shows the percentage change in distance as a function of the temperature of the PDMS substrate. The observed dependence is linear and the linear thermal expansion coefficient can be directly extracted from this measurement, yielding a value αPDMS = (3.4 ± 0.3) · 10−4 °C−1, in good agreement with the value reported in literature.28 One can easily determine the amount of biaxial expansion/compression εSub of the substrate directly from the temperature εSub = αSub (T−25 °C). The thermal expansion of this substrate is roughly 50 times larger than that of TMDCs.5, 29 Therefore, a change in temperature of the substrate is expected to yield a biaxial strain of the TMDCs deposited on the substrate.

We first studied the effect of strain on mechanically exfoliated flakes of monolayer MoS2 deposited on PDMS, a substrate that is commonly used in strain engineering experiments with 2D materials. The flakes have been deposited onto the PDMS substrates by mechanical exfoliation with Nitto SPV 224 tape. Subsequent deterministic placement30 allows one to transfer the flakes from the PDMS to PP and PC substrates. The thickness of the flakes is determined by a combination of quantitative optical analysis, differential reflectance spectroscopy and Raman spectroscopy. Figure 2a shows an optical image of a flake of MoS2 deposited on a PDMS substrate with different numbers of layers of MoS2 showing a different optical contrast. Figure 2b displays the Raman signal, measured at the point indicated in Fig. 1a, which shows two prominent maxima, which are well fitted to Lorentzian functions and attributed to A1g and E12g vibrations of MoS2.31, 32 We find a frequency difference Δf = (19.6 ± 0.2) cm−1 between these vibrations, which confirms that the dark region in the optical image is a monolayer of MoS2, since it is known that Δf increases with the number of layers as shown in the inset of Fig. 2b.

Fig. 2
Fig. 2

a Optical image of a MoS2 flake deposited on a PDMS substrate; the darker violet region is single-layer MoS2. The contour of the flake is outlined by a black dashed line. b Raman spectrum of the MoS2 flake taken at the position of the red square in panel (a). The inset shows the dependence of the difference in Raman shift of the modes A1g and E2g as a function of the number of layers, the red square indicates the value found in this study. c Differential reflectance measured on the single-layer region of the MoS2 flake for zero substrate expansion (light coloured curve) and at 1 % of substrate expansion (dark curve). d Energy of the excitonic peaks A, B in panel (c), extracted from a multi-peak fit as a function of the substrate expansion. The thin lines represent a linear fit to the data, while the thick line represents the same trend after subtraction of the intrinsic thermal dependence contribution

To study the optical properties of the monolayer as a function of biaxial strain, we use a micro-reflectance setup in which we illuminate a small area (diameter ≈ 60 µm) of the sample with a halogen white light source, which is collimated through a small diaphragm and focused with the microscope lens (see Supplementary Information Fig. SI5). Thanks to a fibre optic (core diameter 105 µm) attached to the trinocular, we collect only the light reflected by a small area of the sample (diameter 2.1 µm, see Supplementary Information Fig. SI6). The dimensions of this probed area are much smaller than a typical single-layer region that measures at least 10 × 10 µm. The differential reflectance signal of an ultra-thin film adsorbed on a surface is directly proportional to the absorbance of the film,33, 34 see Supplementary Information section 3. Figure 2c shows differential reflectance spectra acquired on the single-layer region of the MoS2 flakes. The differential reflectance spectra of single-layer MoS2 increase for energies larger than the bandgap (optical band gap: 1.9 eV). On top of a broad background, one finds two prominent maxima centred at 1.90 and 2.05 eV, which correspond to the A and B excitons. Photons are absorbed due to the direct transitions at the K point of the Brillouin zone of monolayer MoS2.35,36,37,38

The differential reflectance spectra have been recorded at room temperature (25 °C) and at 55 °C. This temperature difference causes an expansion of the substrate of approximately 1%. An inspection of the spectra reveals that both the A and B resonances display a redshift of 13 meV for this substrate expansion. To extract the energy of the excitons from Fig. 2c, we fit the peaks present in the differential reflectance spectra with Lorentzian functions. In Fig. 2d, we display the energy shift of the A and B excitons, with respect to the room temperature values, as a function of the thermal expansion of the substrate. The data indicate a linear dependence on the substrate expansion both for tensile and for compressive strain. We find a gauge factor, i.e. the rate of shift in energy of a spectral feature as a function of the substrate percentage expansion/compression, of approximately −13 meV/% (corresponding to −0.44 meV/°C, see Table 1). To test the reproducibility and rule out slippage, we studied the differential reflectance of single-layer MoS2 during consecutive cycles of warming/cooling of the PDMS substrate (see Supplementary Information Fig. SI16, additional measurements on polycarbonate are discussed in the in Fig. SI12).

Table 1 Experimental gauge factors of single-layer MoS2

To investigate the intrinsic effect of the temperature on the optical spectrum of a single layer MoS2 flake, we repeated the warming/cooling experiment using glass as a substrate. Glass has a small thermal expansion coefficient (αGlass = 0.04 · 10−4 °C−1), which is approximately two orders of magnitude smaller than the coefficients of polymeric substrates, resulting in an expected maximum strain attainable of only 0.04% when heating from 10 to 110 °C. Supplementary Information Fig. SI11 shows the differential reflectance spectra of single-layer MoS2 deposited on glass for different temperatures. The A and B excitons redshift for increasing temperature. From a linear fit, we find the intrinsic thermal dependence of the energy of the A and B excitonic peak of monolayer MoS2 equal to −0.34 and −0.42 meV/°C, respectively. These values are in good agreement with previous measurements of MoS2 on SiO2 and of single-layer MoSe2 on SiO235, 39 and are attributed to the redshift of the bandgap energy caused by the thermal expansion of the lattices of these single-layer TMDCs. After subtraction of this intrinsic thermal shift from the measured gauge factor of MoS2 on PDMS, the energy shift of the excitons induced by straining the polymer substrate is between 0 and −2 meV/%. In contrast, our ab-initio calculations of the absorption spectra of MoS2 upon biaxial strain show a much more pronounced shift. We perform density functional theory (DFT) calculations in the local density approximations (LDAs), followed by a GW step within the LDA + GdW approximation,40 to then solve the Bethe–Salpeter equation (BSE) to access absorption spectra. Figure 3 displays our results for a single-layer MoS2 in absence of external strain and with 1% of biaxial tensile and compressive strain. We find a linear dependence of both the A and B excitons. The gauge factors for the quasiparticle gap and the A and B excitons are compared in Table 2. An extended table including the quasiparticle gaps and energetic positions of the A and B excitons can be found in the Supplementary Information (Table SI2). The difference between the calculated gauge factors and those measured using PDMS substrates is a factor of 100 smaller. The fact that the redshift observed for MoS2/PDMS is comparable in magnitude to the one observed for MoS2/glass, even if the strain of PDMS is a factor 50 larger than the strain attainable in glass, together with the large discrepancy between the theoretical and the experimental gauge factors indicate that most of the strain present in the PDMS substrate is not transferred to the adsorbed MoS2 flake.

Fig. 3
Fig. 3

Calculated BSE absorption spectra under biaxial strain of single-layer MoS2 (a). An artificial broadening of 0.035 eV is used in the BSE calculations and the spectra are vertically shifted for improved visibility. The energies of the A and B excitons are extracted from the ab-initio calculations (b)

Table 2 Comparison of the gauge factors of the four single-layer TMDCs deposited on PP

According to previous studies on graphene,27 the efficiency of a substrate to transfer strain to a flake depends on the Young’s modulus of the substrate ESub. The expected maximum strain ε induced in the monolayer TMDCs flakes is typically a fraction of the substrate strain εSub and can be written as:

ε=g ε Sub ,

with g being a dimensionless parameter that depends on ESub and on the lateral size of the monolayer, and has values between 0 and 1.11 This is supported by finite element simulations (shown in Supplementary Information Figs. SI17 and SI18) in which we perform an axisymmetric simulation of a MoS2 flake (diameter 10 µm, height 0.7 nm) on top of a substrate (diameter 500 µm, height 100 µm). We calculate the amount of strain transferred from the expanded substrate to the MoS2 flake (E MoS2 ≈ 350 GPa11) as a function of the substrate’s Young’s modulus and we find for substrates with a Young’s modulus comparable to that of PDMS (E Sub  ≈ 500 kPa) that the strain transferred is on the order of 1% (g = 0.01). To transfer a larger amount of strain, one should use substrates with Young’s moduli larger than 500 MPa. Among the different possible materials, we choose PP as a substrate because of the good trade-off between its thermal expansion coefficient (αPP ≈ 1.35 · 10−4 °C−1) and its Young’s modulus (E PP  ≈ 1.5 GPa), which according to the finite element simulation give a strain transfer efficiency g = 0.75 for a flake of MoS2.

We performed differential reflectance measurements as a function of substrate strain on single-layer flakes of MoS2, MoSe2, WS2 and WSe2 deposited on PP (see Supplementary Information Fig. SI13 for similar measurements performed on PDMS). Figure 4 displays the differential reflectance spectra of the four TMDCs single-layer flakes recorded at zero substrate expansion and at 0.9% of biaxial expansion, and at 0.1% of biaxial compression. All the spectra show maxima attributed to excitons in the materials36, 37 on top of a broad background. An accurate theoretical description of the features present in the optical absorption spectra can be found in Ref. 41. At zero strain and energy lower than 2.2 eV, the Mo-based TMDCs show two peaks, already discussed in the case of MoS2, labelled A and B, whose separation is essentially equal to the spin-orbit splitting of the valence band. In the W-based TMDCs, the A peak is still evident, while the B exciton is less prominent, giving rise to a shoulder in WS2 around 2.4 eV and to a peak at 2.1 eV in WSe2. The larger spin-orbit splitting, due to the heavier W atoms compared to Mo atoms, induces a larger separation of the A and B features in the differential reflectance spectra of W-based TMDCs. The pronounced broad peak at energies above 2.5 eV present in MoS2, MoSe2 and WS2 (C exciton) has been interpreted as coming from nearly-degenerate exciton states, located in regions of the Brillouin zone where the valence and conduction bands are nested. The different and more complicate physical origin of the peak C in respect to the A and B excitonic peaks makes a direct comparison of the behaviour under strain difficult.

Fig. 4
Fig. 4

Differential reflectance spectra of single-layer flakes of the four TMDCs deposited on PP. The spectra have been measured as a function of the substrate expansion (red curves) and contraction (black curves) and are vertically shifted for clarity. Energy of the excitonic peaks (labelled A and B) as a function of substrate strain extracted from the differential reflectance spectra

The A and B features shift to lower energies when the substrate expands and to higher energies for substrate compression. We extract the position of the A and B features as a function of substrate temperature for the four TMDCs and plot the results in Fig. 4. A linear fit to the data allows determining the gauge factors that are listed in Table 2 for each material. The magnitude of the shifts induced by the application of strain follow the order WS2 > WSe2 > MoS2 > MoSe2. Thus, given the same chalcogenide atom (S or Se), W atoms induce a larger gauge factor than Mo atoms, due to their more diffuse d orbitals. Conversely, given the same metal, the lighter S atoms induce a larger shift than Se atoms. These effects and the trend observed are well reproduced by the calculations reported in Fig. 3 and in Supplementary Information Fig. SI20.


Our theoretically obtained gauge factors are systematically higher than our experimental values. In the experiment, as already discussed, only a part of the strain is transferred from the substrate to the monolayer. Therefore, the calculated values are an upper bound for the experimental gauge factors. The ordering of the gauge factors on the other hand for the different materials (WS2 > WSe2 > MoS2 > MoSe2) is perfectly reproduced by our calculations. The magnitudes and ordering of the theoretical exciton gauge factors closely follow the gauge factors of the quasiparticle gap, as can be seen in Table 2, demonstrating that the underlying electronic structure already dictates the ordering. We find that the shift in the gaps under strain mainly stems from the shift of the conduction band minima (CBM). In the CBM, the shifts (with respect to the vacuum energies) are three times as high as in the valence band minima (VBM) for all four TMDCs. The magnitude of the gauge factor ultimately measures how strong the electronic structure of the monolayer reacts to structural change. Strongly overlapping wave functions between atoms would lead to a larger gauge factor. The band width in the conduction band can be taken as a good indicator for the magnitude of the inter-atomic orbital overlap. Comparing the band width of the lowest conduction band around the K point (within a distance of 0.2 π/a from K, the area of momentum space, which is mainly responsible for the A and B excitons), we find the ordering WS2 (0.30 eV) > WSe2 (0.26 eV) > MoS2 (0.20 eV) > MoSe2 (0.18 eV) that follows the same ordering of the exciton gauge factors discussed previously. In conclusion, this suggests that the magnitude of the gauge factor, which mainly stems from the change in the CBM with strain, is largest for a strong overlap between atoms, which can be estimated through the band width around the K point. We notice that for the values of biaxial strain investigated, the four single-layer TMDCs remain direct gap semiconductors.4, 13, 18, 39, 42

The strain-induced shift of the excitonic peaks in the differential reflection spectra of single-layer TMDCs is particularly interesting for applications as optical modulators. By controlling the temperature of the polymeric substrate, we can easily tune the position of the excitonic peaks and achieve a 10% modulation of the reflection for certain wavelengths in a time-scale of a few seconds. We record the differential reflectance of a MoS2 single-layer flakes deposited on PP while cycling the temperature between 30 and 75 °C, applying a square wave modulated voltage to the Peltier heater. Figure 5a displays the differential reflectance at an energy of 1.91 eV, corresponding to a wavelength of 648 nm, recorded as a function of time with a resolution of 300 ms. The reflectance has a distorted square wave profile with rise/fall characteristic times of 10 s with a modulation of the intensity of 8% at 648 nm. This timescale is limited by the heat transfer between the Peltier heater and the polymeric substrate, and could be improved by using local micro-heaters. Figure 5b displays the position of the A exciton peak as a function of time. The reproducibility in the shift and the transfer rate of the strain are excellent. The observed modulation in the signal of the order of 10% (at specific wavelengths) is noteworthy especially considering the atomic thickness (<1 nm) of these single-layer TMDCs. Modulations up to 25% can be reached thanks to the excitons that dominate the dielectric function of single-layer TMDCs materials, which are present at room temperature.

Fig. 5
Fig. 5

a Differential reflectance measured at a wavelength of 648 nm on single-layer MoS2 deposited on PP as a function of time with periodical heating and cooling cycles of the substrates from 30 to 75 °C. Each differential reflectance spectrum has been integrated for 300 ms. b Energy of exciton A as a function of time

In conclusion, we have exploited the large thermal expansion coefficient of a polymer substrate to apply large biaxial tensile strain on single-layer flakes of four TMDCs. By recording the exciton-dominated differential reflectance spectra of these materials as a function of external strain, we monitored the change in bandgap induced by the strain. We observe that the magnitude of the induced energy shift is the largest with WS2 flakes where it reaches 95 meV/%. The shift follows the order MoSe2 < MoS2 < WSe2 < WS2. Theoretical calculations reproduce well the experimental results and the observed trend in the various materials for the dependence of the bandgap on the external strain. The large shift induced in the bandgap by biaxial strain and the rapidity for the transfer of strain open the possibility for the use of 2D TMDCs as electro-optical modulators or strain sensors.


Differential reflectance measurements

White light from a halogen lamp irradiates the sample after passing through a small diaphragm and results in an illumination spot of approximately 50 μm at the sample surface. The light reflected from the sample is collected with an optical fibre (105 μm core diameter) and fed to a spectrometer. The fibre is used to collect only the light reflected from a few μm area of the sample located approximately in the center of the illumination spot. The differential reflectance spectrum of a TMDC flake is calculated by subtracting from the reflectance spectrum collected on top of the flake the same spectrum collected on the substrate, and normalising the result by the flake spectrum.

Ab-initio calculations

We performed ab-initio DFT calculation in the LDA, from which we obtain the energetically optimised structure. The DFT wave functions and energies are then used as input for a subsequent GW calculation within the LDA + GdW approximation,36 in which the dielectric screening properties are described by an atom-resolved model function based on the random-phase approximation.36 In the last step, the BSE is set up from the quasiparticle band structure. For the given TMDC monolayers, excitons are composed from four valence and six conduction bands and a mesh of 30 × 30 × 1 k points from the first Brillouine zone. To simulate biaxial tensile (compressive) strain, the lattice constant is increased (decreased) fully relaxing the structure for each applied strain. All further numerical details can be found in the Supplementary Information. This approach has already been successfully used to describe uniaxial strain in a WSe2 monolayer.19


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We thank Dr. Isabel Rodriguez for the nanoimprinted PDMS substrates and Dr. Emilio Pérez Alvarez and Alejandro López Moreno for their help with the Raman measurements. We acknowledge financial support from the European Commission, the MINECO, the Comunidad de Madrid and from the Netherlands Organisation for Scientific Research (NWO). M.D. thanks the Studienstiftung des deutschen Volkes for support via a PhD fellowship. The authors gratefully acknowledge the computing time granted by the John von Neumann Institute for Computing (NIC) and provided on the supercomputer JURECA at Jülich Supercomputing Centre (JSC). A.C.G. European Commission under the Graphene Flagship: contract CNECTICT-604391 A.C.G. MINECO: Ramón y Cajal 2014 program RYC-2014- 01406 A.C.GG. MINECO: progeam MAT2014-58399-JIN A.C.G. Comunidad de Madrid: MAD2D-CM program (S2013/MIT-3007) R.F. Netherlands Organisation for Scientific Research (NWO): Rubicon 680-50-1515 D.P.dL. MINECO: program FIS2015-67367-C2-1-p.

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Author notes

    • Andres Castellanos-Gomez

    Present address: Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Campus de Cantoblanco, E-28049, Madrid, Spain


  1. Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA-nanociencia), Campus de Cantoblanco, E-28049, Madrid, Spain

    • Riccardo Frisenda
    • , David Perez de Lara
    •  & Andres Castellanos-Gomez
  2. Institute for Solid-state Theory, University of Münster, D-48149, Münster, Germany

    • Matthias Drüppel
    •  & Michael Rohlfing
  3. Institute of Physics and Center for Nanotechnology, University of Münster, D-48149, Münster, Germany

    • Robert Schmidt
    • , Steffen Michaelis de Vasconcellos
    •  & Rudolf Bratschitsch


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R.F. and A.C.G. carried out the strain experiments. R.F analysed the experimental data. M.D and M.R. performed the ab-initio calculations. A.C.G. and D.PdL. designed the experiment. R.S., S.M.dV. and R.B. performed the finite element simulations. All the authors discussed the results and contributed to the writing of the manuscript.

Competing interests

The authors declare that they have no competing financial interests.

Corresponding authors

Correspondence to Riccardo Frisenda or Michael Rohlfing or Andres Castellanos-Gomez.

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