Abstract
In this work, a high thermoelectric figure of merit, zT of 1.9 at 740 K is achieved in Ge_{1−x}Bi_{x}Te crystals through the concurrent of Seebeck coefficient enhancement and thermal conductivity reduction with Bi dopants. The substitution of Bi for Ge not only compensates the superfluous hole carriers in pristine GeTe but also shifts the Fermi level (E_{F}) to an eligible region. Experimentally, with moderate 6–10% Bi dopants, the carrier concentration is drastically decreased from 8.7 × 10^{20} cm^{−3} to 3–5 × 10^{20} cm^{−3} and the Seebeck coefficient is boosted three times to 75 μVK^{−1}. In the meantime, based on the density functional theory (DFT) calculation, the Fermi level E_{F} starts to intersect with the pudding mold band at L point, where the band effective mass is enhanced. The enhanced Seebeck coefficient effectively compensates the decrease of electrical conductivity and thus successfully maintain the power factor as large as or even superior than that of the pristine GeTe. In addition, the Bi doping significantly reduces both thermal conductivities of carriers and lattices to an extremely low limit of 1.57 W m^{−1}K^{−1} at 740 K with 10% Bi dopants, which is an about 63% reduction as compared with that of pristine GeTe. The elevated figure of merit observed in Ge_{1−x}Bi_{x}Te specimens is therefore realized by synergistically optimizing the power factor and downgrading the thermal conductivity of alloying effect and lattice anharmonicity caused by Bi doping.
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Introduction
Thermoelectric (TE) materials enable the direct energy conversion between heat and electricity that are of great interest in the field of waste heat recovery and solidstate cooling according Seebeck and Peltier effects, respectively. The conversion efficiency is mainly determined by the dimensionless figure of merit zT = σ S^{2}T/κ, in which σ, S, T, κ and σ S^{2} are the electrical conductivity, Seebeck coefficient, absolute temperature, thermal conductivity, and power factor (PF), respectively. These parameters are strongly coupled with each other, leading to the difficulty in manipulation of zT enhancement^{1}. To achieve a high zT value, band engineering approaches including band convergence^{2}, dimensionality reduction^{3}, resonant levels^{4}, low band effective mass^{5}, minority carrier energy filtering^{6}, dislocations^{7}, 2dimensional electron gas^{8}, have been proposed to improve the performance of electronic contribution, while nanostructuring^{9}, multiscale microstructuring^{10}, lattice anharmonicity^{11,12}, rattling atoms^{13}, liquid phonons^{14}, lattice disorder^{15}, and interstitial point defects^{16,17} are strategies commonly used for minimizing thermal conductivity of lattice contribution.
To date, groupIV monochalcogenidesbased compounds are considered to be the leading TE materials in intermediate temperature range (600–923 K)^{18,19}. Among them, GeTe is a heavily ptype semiconductor with an inherent high carrier concentration of ~10^{21} cm^{−3}. It stabilizes in a noncentrosymmetric rhombohedral structure with an space group R3m (No. 160) at room temperature, which undergoes a secondorder ferroelectric phase transition to a cubic structure (Fm \(\bar{3}\) m) at 600–700 K, accompanied by an angle distortion of the unit cell from ~57.5° to 60°. The transition temperature depends on the sample stoichiometry and carrier concentration^{20}. Its maximum zT is close to 1.0 near 700 K. Recently, several pseudobinary system have been found to exhibit zT > 1.75 between 600–800 K^{21,22,23,24}. Besides Sb and Pb, Bi is also a good dopant in this system, i.e., zT = 1.3 for Ge_{0.94}Bi_{0.06}Te melt ingot at 700 K^{25}. However, in some cases polycrystalline or single crystals show much better thermoelectric properties as compared to that of the melt ingots. The innovation of this work is that we applied the Bridgman method to grow Ge_{1−x}Bi_{x}Te crystalline samples, and found an extraordinary high zT of 1.9 (700~740 K) in the Bridgmangrown Ge_{0.9}Bi_{0.1}Te crystal.
Results and Discussion
The image of as grown Ge_{1−x}Bi_{x}Te ingots are shown in Fig. 1(a). These samples are ~40 g in weight with 13 mm in diameter. They have a rhombohedral lattice at room temperature (the inset in Fig. 1(d)) and are free from secondary phases, as confirmed by the powder Xray diffraction (XRD) patterns (Fig. 1(b)). With increasing Bi content, the XRD peaks between 42°–44° merge that signifies the increasing cubic nature of Ge_{1−x}Bi_{x}Te structure. From XRD Rietveld refinement, as x increases, the lattice parameters of a and b increase while the lattice parameter c decreases monotonically (Fig. 1(c)). Though the ionic radius of Bi is larger than that of Ge, the volume of Ge_{1−x}Bi_{x}Te unit cell is nearly invariant with x. This causes the increase of crystal density from ~6.14 g cm^{−3} to 6.58 g cm^{−3}, as shown in Fig. 1(d). The thermal stability of samples can also be examined by xray diffraction in thermal cycles. Here we carried out the temperature dependence of XRD to check the thermal stability of the Bi doped GeTe samples, for example of Ge_{0.9}Bi_{0.1}Te (Supplementary Fig. S1), as the sample was heated to 700 K, the diffraction peaks remained the same, thus confirmed the thermal stability of Ge_{0.9}Bi_{0.1}Te.
For pristine GeTe, the inherently high carrier concentration of n_{H}~8.7 × 10^{20} cm^{−3} makes the Fermi level (E_{F}) falls deeply into the valence band, as shown by the black line in Fig. 2(a), where we show the DFT calculated band structure for the pristine GeTe. The intersections of E_{F} with L and Σ create hole pockets with large Fermi surfaces that leads to its metallic nature. When the Bi content x increases from 0 to 0.12, the n_{H} reduces from 8.7 × 10^{20} cm^{−3} to 0.7 × 10^{20} cm^{−3} due to the carrier compensation given by the excess electrons from Bi. For a metallic system, Seebeck coefficient at temperature T can be described by Mott’s relation^{26}:
where k_{B}, q and N(E) are Boltzmann constant, elementary charge, and energy dependent density of state (DOS) near E_{F}, respectively. Certainly, a large Seebeck coefficient can be brought by a low N(E) coupled with a steep slope of ∂N(E)/∂E near E_{F}. Note that as the E_{F} intersects with the “pudding mold valley” at L point when n_{H}~3–5 × 10^{20} cm^{−3} (the cyan region in Fig. 2(a))^{27,28,29}, the Seebeck coefficient becomes extremely large and effectively compensates the degradation of electrical conductivity and thus successfully maintains the power factor as large as or even superior than that of the pristine GeTe. The calculated Seebeck coefficients (the orange dashed line in the Fig. 2(b)) were obtained based on the pristine GeTe electronic structure with the BoltzTraP code using rigidband and constantrelaxationtime approximations^{30}. It can be found that the trend of the calculated Seebeck coefficients are consistent with the experimental values. Besides the energy dependent density of state N(E), the effective mass is another factor that has an important influence on the Seebeck coefficient. Hence, the relationship between the carrier concentration and Seebeck coefficient of Ge_{1−x}Bi_{x}Te was plotted in Fig. 2(b), and the fitting results derived from the single parabolic band model with the effective mass of 1.1, 1.5, 2.0, and 2.3 m_{0} were presented. Apparently, the effective mass of Bi doped GeTe samples drastically increases from 1.1 m_{0} to 2.3 m_{0}, partly explaining the enhanced Seebeck coefficient. The DFT calculation with 7.4% Bi doping shows a reduced energy difference between the L band and the band in the XΓ direction (the dashed yellow rectangle in the inset of Fig. 2(a) and Supplementary Fig. S2^{31,32}). This will lead to multiple band transport and enhancing the effective mass, which benefits for electrical transport that qualitatively consistent with the experimental result.
Figure 3 gives the thermoelectric properties of Ge_{1−x}Bi_{x}Te with x = 0–0.12 measured in 300–740 K. The σ of all samples decreases with increasing temperature, indicating a degenerated semiconductor behavior (Fig. 3(a)). At room temperature, the σ decreases from 8.02 × 10^{5} S m^{−1} to 1.57 × 10^{5} S m^{−1} as x increases from 0 to 0.1. As x further increases to 0.12, a dramatic reduction of ~97% in σ occurs. This can be attributed to the significant reduction in Fermi surface (or DOS) when the E_{F} escapes the L band. Figure 2(a) shows that the Fermi level E_{F} of Ge_{0.88}Bi_{0.12}Te merely intersects with the Σ band, represented by the orange line, where the DOS (with n_{H}~0.75 × 10^{20} cm^{−3}) is greatly reduced. Consequently, only a slight variation in hole concentration will cause a more pronounced E_{F} shift. Besides, Bi alloyings do reduce the carrier mobility, and can be presumably attributed to the additional scattering of alloying effects (Supplementary Table S1). This phenomenon is normally seen in similar materials such as SnTe, PbSe, and PbTe. Contrary to the σ, the S shows an upward tendency with the increasing Bi content, as shown in Fig. 3(b). The S of all samples are positive in the whole temperature range, indicating that holes are the dominant charge carriers in this alloying system. In principle, the S of all samples increases with temperature increase. For Ge_{0.88}Sb_{0.12}, a flat S plateau is observed as T > 550 K, which infers the enhanced bipolar effect arisen from the massive carrier compensation. The point can be further confirmed by the σ, which starts to increase as T > 550 K and become nearly invariant for all Bi doped samples, the phenomenon is more obvious for x ≥ 0.06 specimens. It is noticed that the tradeoff between the σ and S can significantly bring down the thermal conductivity of carriers while keeping the high value of PF (Fig. 3(c)). Compare to the undoped GeTe, the PF of x = 0.6, 0.8, 1.0 samples below 600 K are greatly enhanced, while for x = 0.12, the temperaturedependent PF curve drops dramatically due to the significant reduction in σ. The pristine GeTe has a high κ of ~8.6 W m^{−1} K^{−1} at room temperature, which decreases with increasing temperature and reaches the minimum value of 4.1 W m^{−1} K^{−1} near phase transition point at ~670 K which is clearly reflected in the discontinuity in κ (Fig. 3(d). With the increasing Bi content, the κ is substantially reduced. For instance, Ge_{0.88}Bi_{0.12}Te has the κ value of ∼1 W m^{−1} K^{−1} and 1.2 W m^{−1} K^{−1} at 300 K and 740 K respectively, which have about 88% and 71% reduction with respect to that of pristine GeTe. Such substantial reduction in thermal conductivity for Ge_{1−x}Bi_{x}Te crystals is very helpful in boosting the zT value. It is known that the total thermal conductivity κ_{tot} is the sum of the electronic contribution κ_{e} and the lattice contribution κ_{lat}. The plot of κ_{e} as a function of temperature for all samples is presented in Fig. 4(a), suggesting that the heat transport of pristine GeTe is mainly (~65%) from carrier contribution. With Bi doping, the κ_{e} was significantly decreased by reducing the ptype carrier concentrations. κ_{lat} is then calculated from κ_{tot} by subtracting κ_{e} (Fig. 4(b)). At 740 K, the κ_{lat} of pristine GeTe is ~1.9 W m^{−1} K^{−1}, whereas it is only ~0.7 W m^{−1} K^{−1} for x = 0.1 of Bi, showing a 63% reduction in κ_{lat}. κ_{lat} decreases rapidly with increasing Bi doping, which can be attributed not only to the enhanced alloy scatterings but also to the lattice anharmonicity that will be discussed later.
In addition to the minimized carriercontributed thermal conductivity and alloying effect, the anomalously low and nearly temperature independent thermal conductivity is also attributed to the large lattice anharmonicity introduced by long pair electrons of Bi cation^{33,34}. The valence electronic configuration of Bi is 4f^{14}5d^{10}6s^{2}6p^{3} prefers to form stereochemically active lone pair electrons in many materials. The electrostatic repulsion between the lone pair electrons and the relevant bonding charges have been confirmed to the origin of strong anharmonic phononphonon interactions which is able to reduce the lattice thermal conductivity to the nearly amorphous limit. To understand the mechanism of strong anharmonic phononphonon interaction of Bi ions in GeTe, further systematical studies are required. Figure 5 shows the temperature dependence of zT for all Ge_{1−x}Bi_{x}Te specimens. Apparently the zT values are significantly boosted by Bi substitution at all temperatures. At highest available temperature T = 740 K, the zT remarkably achieve the values of 1.5, 1.6, 1.9 and 1.4 for x = 0.06, 0.08, 0.1, 0.12 respectively. Especially, a flat plateau of zT~1.9 is establish in Ge_{0.9}Bi_{0.1}Te when >700 K. It is also noted that the largest zT value in this paper is as high as 1.9, which is about 46% higher than zT = 1.3 reported^{25}. The key point is that the elevated zT in Ge_{1−x}Bi_{x}Te specimens prepared by Bridgman method is realized by synergistically optimizing the power factor and downgrading the thermal conductivity of alloying effect and lattice anharmonicity caused by Bi doping. In addition, the thermoelectric data for Ge_{0.9}Bi_{0.1}Te were repeated for a couple of times, and the narrow statistic distribution of zT values clearly confirms the repeatability.
Conclusions
In summary, the substitution of Ge by Bi in GeTe enables an exquisite manipulation of carrier concentration n, Fermi level E_{F} and thermal conductivity κ to optimum values that raise the zT of Bidoped Ge_{1−x}Bi_{x}Te specimens for x = 0–0.12. The combination of theoretical calculations and experimental results elucidates the interrelations between σ, S and band valleys. Due to the substantial reduction in κ, the zT of all Bi doped Ge_{1−x}Bi_{x}Te specimens are greatly enhanced. A remarkable zT of 1.91 at 740 K is achieved in the specimen of Ge_{0.9}Bi_{0.1}Te, which is comparable to the stateoftheart high performance thermoelectric material systems.
Methods
High purity elements of Ge (99.999%), Te (99.999%) and Bi (99.999%) were weighted according to the stoichiometric ratio of Ge_{1−x}Bi_{x}Te (x = 0, 0.06, 0.08, 0.10, 0.12), and sealed in evacuated silica tubes. The silica tubes were then heated at 1123 K for 48 hours followed by furnace cooling to room temperature. Ge_{1−x}Bi_{x}Te crystals were then grown by using Bridgman method from the premelt ingot, with a growth rate of 3 mm h^{−1} at 1123 K. The crystal structure of Ge_{1−x}Bi_{x}Te was determined by a PANalytical® X’Pert PRO Xray diffraction diffractometer (λ = 1.54056 Å). The electrical conductivity and Seebeck coefficient were measured using the ULVAC ® ZEM3 system. The uncertainty of the Seebeck coefficient and electrical conductivity measurements is about 2~4%. The thermal diffusivity of samples was measured on a NETZSCH LFA 457 laser flash instrument (Supplementary Fig. S3) and the thermal conductivity was calculated from the relationship κ = αC_{p}d, where α is the thermal diffusivity, C_{p} is the heat capacity according to the DulongPetit law, and d is the mass density, measured by Archimedes’ method. The difference between calculated heat capacity and the measured value is less than 5%, and insure the validity of DulongPetit value for the C_{p.} The uncertainty of the thermal conductivity was estimated to be ~5%. Considering the uncertainties for Seebeck coefficient, electrical conductivity and thermal conductivity, the combined uncertainty of zT is less than 15%. The carrier concentration was estimated using the relation p = 1/eR_{H}, where R_{H} is the Hall coefficient measured by Quantum Design® Physical Properties Measurement System. The uncertainty of the Hall coefficient is ~3%. The firstprinciples density functional theory (DFT) calculations with spinorbit coupling effect were performed using projector augmentedwave (PAW) potentials^{35,36,37}, as implemented in the Quantum Espresso package^{38}. The exchangecorrelation functional was treated by the generalized gradient approximation with the Perdew–Burke–Ernzerhof form^{39}. The experimental lattice constants was used with their atomic positions fully relaxed and the kinetic energy cutoff of 750 eV. The Seebeck coefficients were calculated using the BoltzTraP code^{30}.
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Acknowledgements
This work is financially supported by Ministry of Science and Technology (MOST), Taiwan, Grant No. MOST 1062112M001 019 MY3.
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P.C.W., C.L.C., and Y.Y.C. conceived the idea, analyzed the results and wrote the paper. C.X.C. prepared the samples and performed the thermoelectric property measurements. C.R.H., D.L.N. and C.M.W. carried out the theoretical calculations; S.H.Y., H.J.W., M.M.C.C. and D.H.W. provided the technical supporting for experiments.
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Enhancing thermoelectric performance by Fermi level tuning and thermal conductivity degradation in (Ge1xBix)Te crystals
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Wei, PC., Cai, CX., Hsing, CR. et al. Enhancing thermoelectric performance by Fermi level tuning and thermal conductivity degradation in (Ge_{1−x}Bi_{x})Te crystals. Sci Rep 9, 8616 (2019). https://doi.org/10.1038/s41598019450719
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DOI: https://doi.org/10.1038/s41598019450719
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