Sodium ion batteries meet the demand for large-scale energy storage, such as in electric vehicles, due to the material abundance of sodium. In this report, nanotube-type Na2V3O7 is proposed as a cathode material because of its fast sodium diffusivity, an important requirement for sodium ion batteries, through the investigation of ~4300 candidates via a high-throughput computation. High-rate performance was confirmed, showing ~65% capacity retention at a current density of 10C at room temperature, despite the large particle size of >5 μm. A good cycle performance of ca. 94% in capacity retention after 50 cycles was obtained owing to a small volumetric change of <0.4%.
Sodium ion batteries (SIBs) are attractive alternatives for lithium ion batteries, which are currently preferred as power sources for environment-friendly large-scale batteries1,2,3. Sodium has a high ionization tendency comparable to that of lithium, which leads to high energy densities of SIBs4. Moreover, sodium resources are not limited; they are abundant in the earth’s crust as well as in seawater, ensuring a stable supply of SIBs to meet the increasing need for large-scale batteries5. Another expected advantage of SIBs is their higher sodium diffusivity compared to that of lithium due to weak interactions between alkaline ions and counter anions4. Thus, high rate performance— which is a critical requirement for electric vehicle applications6—is expected with appropriate crystal structure engineering.
In this paper, the Na2V3O7 compound is suggested as a cathode material for SIB. This compound was chosen due to its expected high sodium diffusivity, predicted through high-throughput computations of sodium migration energies among 4314 compounds using the bond valence force field (BVFF) approach7 (Fig. 1(a)). Additionally, its sufficient theoretical capacity (~173 mAh g−1) and novelty (there have been few reports on its electrochemical performance, as mentioned later) are attractive. This compound was synthesized by P. Millet et al.8. One of the crystal structure features of Na2V3O7 is the formation of one-dimensional nanotubes consisting of VO5 square-pyramidal networks. These nanotubes are aligned as honeycomb structures, and the sodium ions are distributed inside and on the peripheries of the nanotubes. Therefore, the sodium ions inside and on the peripheries of the tubes diffuse one- and three-dimensionally, respectively, and the high-throughput computations predicted small migration energies for both routes (Fig. 1(b–d)). The nominal charge of V is +4 and thus a high voltage V4+/5+ redox reaction is expected accompanying sodium removal and insertion through intercalation. Hereinafter, we show the electrochemical performance and the crystal and electronic structure analyses of Na2−xV3O7 compounds as cathode materials for SIBs. Very recently, electrochemical measurements for Na2V3O7 cathode materials have been reported by Adamczyk et al. and in our previous work, confirming their rechargeable charge-discharge properties9,10. In this report, we present high rate and stable cycle performances, and the origin of these electrochemical performances is discussed thorough experimental and computational structure analyses.
Structure of synthesized Na2V3O7 powder
Figure 2(a) and Supporting Table S1 show the Rietveld analysis results for the synchrotron X-ray diffraction (XRD) pattern of the synthesized Na2V3O7 powder. We confirmed the formation of a nanotube-type structure, as reported in a previous paper8 (Fig. 2(b)). Note that the weighted-profile R-factor (Rwp) was improved by adding one sodium site (Na4 site) at the periphery of the nanotubes to the previous model8 (See details in Supporting Tables 1), where the presence of the Na4 site is indicated by a first-principles molecular dynamics (FPMD) simulation mentioned later in Supporting Section S2 and in Supporting Figure S5. By introducing Na4 sites, sodium ion occupancy of the Na1 site (inside nanotube) decreased from unity to ~0.5 in this study. Figure 2(c) shows a scanning electron microscope (SEM) image of the synthesized Na2V3O7. The particles had needle-shaped bodies with short-side sizes of ca. 5 µm and long-side sizes of ca. 30 µm. These sizes were one order of magnitude larger than the conventional sizes of the electrode particles for SIBs11,12,13. A transmission electron microscope (TEM) image and its selected area electron-diffraction pattern of the needle-like Na2V3O7 powder show that needle growth direction corresponds to the c-axis of Na2V3O7 (Supporting Figure S1). Because of the much longer diffusion distance along the c-axis, Na diffusion on the ab plane plays an important role.
Characterization of Na2V3O7 electrodes
Figure 3(a) shows charge-discharge curves of the cell at a constant current density of 0.1C at 30 °C (C-rate is defined as the current to discharge the theoretical capacity in 1 hour: 1C) The Na2V3O7 electrode exhibited a reversible capacity of about 90 mAh g−1, and a sharp voltage increase followed when a voltage cutoff condition of 3.5 V vs. Li+/Li was reached. This voltage increase was attributed to Na/vacancy ordering at the composition x = 1 in Na2−xV3O7, as mentioned later. Indeed, the observed capacity corresponded to almost half of the theoretical capacity, ~173 mAh g−1, for 2 mol desodiation from the Na2V3O7 compound. We confirmed that the structural topology was roughly unchanged from the XRD profiles during sodium extraction (Fig. 4(a,b)) and a gradual edge-energy increase in the V K-edge X-ray absorption near edge spectra (XANES) (Fig. 4(c,d)), indicating a reversible sodium intercalation reaction process accompanying V redox (V4+/5+). These were supported by first-principles DFT calculations with genetic algorithm (GA) optimization of the sodium/vacancy arrangement (see details in Supporting Section S1). Figure 5 shows (a) the calculated formation energies for Na2−xV3O7 in which the total electron energies for the end compositions (x = 0 and 2) were set to zero, (b) the calculated voltage profile, and (c) occupancies of sodium ions for Na1–Na5 sites as functions of composition x in Na2−xV3O7. The calculated voltage curves also agree with the experimental results (see Fig. 3(a)). During the early stages of desodiation (0 ≤ x ≤ 1/6), the sodium ions inside the nanotube (Na1 site) were removed due to instability and thus the voltages (2.7 V) were lower than the following desodiation process (>3.0 V for 1/3 ≤ x ≤ 1) in which sodium ions were removed from nanotube-fringe sites (Na2-Na5 sites). After desodiation from tunnel sites, electrochemical sodium removal from nanotube-fringe sites showed two voltage steps at ~3.0 V and >4.0 V before and after desodiation to x = 1, respectively. Since there were no significant changes in the V3O7 framework and the redox mechanism of V ions (3+/4+) at composition x = 1.0, we inferred that the calculated voltage change was due to ordering of the Na/vacancy arrangement. Indeed, the ordered arrangement was indicated in the GA optimization at x = 1, where all the Na5 sites were vacant, while the rest of the nanotube-fringe sites (Na2–Na4) were occupied by sodium ions. This was confirmed by first-principles molecular dynamics (FPMD) simulations, mentioned later in Supporting Section S2. The averaged Bader charges14 of V ions shown in Supporting Figure S4 showed a monotonic increase, whereas no marked changes occurred on the Na and O ions (not shown). Thus, vanadium ions were responsible for the redox reaction of the charge/discharge reaction, which agreed with the XANES spectra shown in Fig. 4(c,d).
Figure 3(b) shows galvanostatic discharge capacities with various current densities (using units of C-rate). The C-rate increased gradually every 4 cycles from 0.1 C to 10 C, and then 0.1 C cycling was repeated. Remarkably good capacity retention of ~65% (against the initial capacity at 0.1 C) was obtained even at 10 C, corresponding to full discharge within 6 minutes. Good rate performance was confirmed through comparison with other representative cathodes for SIBs11,12,13,15,16,17,18, as shown in Fig. 3(c). Figure 3(d) shows the cycle performance of the Na2V3O7 electrode at a current density of 1 C. The Na2V3O7 electrode also exhibited excellent cycle performance in which the capacity retentions were ca. 94% at the 50th cycle. The coulombic efficiency was almost 100% up to 50 cycles. This was confirmed by comparison of capacity degradation with those of other representative cathodes11,12,15,16,17,19,20, as shown in Fig. 3(e), which indicated a small capacity fade per cycle for Na2V3O7. The good cycle performance arises from the small volumetric change in the V3O7 host lattice, ca. −3.2 vol% at 3.8 V, which was calculated using the lattice parameter change obtained from ex-situ XRD profiles (Supporting Table S2). A SEM image of the Na2V3O7 electrode after the 50 charge-discharge cycles also indicated that the tube structures of the as-prepared Na2V3O7 particles remained (Supporting Figure S3). Note that the present results show much better rate and cycle performances than the recent work by Adamczyk et al.9. We inferred that the difference stems from (1) the higher charge cutoff voltage (4.5 V) than the present condition (3.5 V), which causes slow Na+ diffusion, as mentioned later, and (2) inclusion of the impurity phase, Na9V14O35 (7%), in the recent report9.
As mentioned above, the observed reversible capacity was half of the theoretical value at the upper cutoff voltage of 3.5 V. The galvanostatic intermittent titration technique (GITT) was used to obtain the open circuit voltage and polarization (overvoltage) of the highly desodiated region, x > 1 in Na2−xV3O7, as shown in Fig. 3(f). Further charging was confirmed for x > ~1 accompanying large polarization, indicating that slow kinetics regulate the capacity. Figure 5(d) displays the variation of the MD-derived diffusion coefficients of Na versus composition x (0.33 ≤ x ≤ 1.33) at a temperature of 1073 K (see details in Supporting Section S2). A significant decrease in the sodium diffusion coefficient was indicated at x > ~1 in Na2−xV3O7 where the Na5 sites were almost empty, which agrees with the results of the AC impedance measurements (Supporting Section S3 and Supporting Figure S6). The sharp drop in sodium diffusivity at x > ~1 was ascribed to Na/vacancy ordering from the computational results of the GA-derived structure and FPMD-averaged structures (Fig. 5(c)), which prevented further desodiation.
In summary, the Na2V3O7 compound, which was selected among ~4300 candidates due to fast sodium diffusivity via a high-throughput computation, was evaluated as a cathode material for SIBs. This compound showed excellent rate performance and cyclability, though the capacity was limited to half of the theoretical capacity (~173 mAh g−1). Since the ordering of Na/vacancy prevented further sodium extraction, doping with appropriate cations or anions would disturb the orderings and improve the capacity. The observed good rate and cycle performances were confirmed for a large particle size of ~5 μm (Fig. 2(c)). Thus, it is expected that nanoparticle synthesis of this compound will largely improve the electrochemical performance of SIBs.
The Na2V3O7 material was synthesized by a solid-state reaction method based on a previous report8. First, Na2CO3 (purity 99.8%, Wako) and V2O5 (99.0%, Wako) powders were mixed in a 4:3 molar ratio. The powder was pelletized and then heated at 650 °C for 1 h to prepare precursor Na4V3O7. The Na4V3O7 and V2O5 mixture and V2O3 (99.0%, Kojyundo Kagaku) powder were mixed in an Ar-filled glove box to yield a chemical composition of Na2V3O7. The mixture pellet was covered with Au foil and sealed under a vacuum in a silica tube. Na2V3O7 was prepared by sintering the pellet at 700 °C for 24 h. All sample manipulations were conducted under an inert gas atmosphere, unless specifically mentioned.
Powder X-ray diffraction experiments were conducted at BL5S2 of the Aichi Synchrotron Radiation Center, Japan. The sample powders were packed in a 0.3 mm diameter borosilicate glass capillary tube and sealed with an epoxy plastic in an Ar-filled glove box. Diffraction measurements were performed in transmission geometry using X-rays with 0.8 Å wavelengths. Diffraction data were collected in 0.01° steps from 4° to 94.91° in 2θ with a scan rate of 2.37° min−1. The computer program RIETAN-FP21 was used for the Rietveld analysis. The synthesized Na2V3O7 particles were observed using a scanning electron microscope (SEM; JEOL, JSM-6360LV). The accelerating voltage was 20 kV.
Electrochemical performances were investigated for 2032-type coin cells using charge-discharge equipment (VMP3, Bio-Logic). Composite cathodes were prepared by mixing the Na2V3O7 active material, Ketjenblack conductive additive, and polyvinylidene fluoride binder at an 8:1:1 weight ratio in N-methyl-2-pyrrolidone. The slurry was cast on an Al foil with an average loading of ca. 1.2 mg cm−2 and dried at 110 °C overnight in a vacuum prior to use. Propylene carbonate with 1 M NaClO4 and 2 wt% fluoroethylene carbonate was used as the electrolyte solution. The cells were assembled with Na anodes and cycled galvanostatically at different current rates at 30 °C in the voltage range of 1.5–3.5 V. The Na reference electrode was also introduced to analyse cell resistances. The overvoltage was quantified by the galvanostatic intermittent titration technique (GITT). The cells were charged for 1 h at a current density of 0.05 C and relaxed for 5 h. The relaxation time was changed to 10 h for voltages over 3.3 V because the relaxation of overvoltage was slow. The resistance was separated and analysed by AC impedance measurements. The applied voltage and measurement frequencies were 10 mV and 1 mHz–0.5 MHz.
Structure analysis for Na2−xV3O7 electrodes
XANES measurements for the charged Na2−xV3O7 electrodes were carried out at the BL5S1 beam line of the Aichi Synchrotron Radiation Center, Japan. The electrodes were prepared by charging to correspond to the compositions, washing with propylene carbonate, and drying at 70 °C overnight. The V K-edge spectra were obtained in transmission mode at room temperature. XRD measurements for the electrode after the charge and discharge processes were conducted with Ni powders as internal standards for peak positions. The electrodes were washed with propylene carbonate and dried at 70 °C overnight. These samples were sealed with polyethylene films and measured by an X-ray diffractometer (Mini Flex 600, Rigaku) using Cu-Kα radiation. Crystal structure diagrams were drawn with Visualization for Electronical and Structural Analysis (VESTA)22.
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This work was supported by the “Elements Strategy Initiative to Form Core Research Center” of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan (Since 2012) and by the “Materials research by Information Integration” Initiative (MI2I) project of the Support Program for Starting Up Innovation Hub from Japan Science and Technology Agency (JST). We also thank the Information Technology Center of Nagoya University for providing computing resources (CX400). Crystal structure diagrams were drawn with Visualization for Electronical and Structural Analysis (VESTA).