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VIBRATIONAL SPECTROSCOPY

Bonds from bands

[FeFe]-hydrogenases are enzymes that catalyse the interconversion of protons, electrons and dihydrogen. Hydrogenase mechanisms have inspired many strategies to produce H2 as a ‘green fuel’. A landmark study from 15 years ago established much of what we know about these intricate mechanisms.

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Fig. 1: The [FeFe]-hydrogenase active site and FTIR spectra of some of its redox states.

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Correspondence to Sven T. Stripp.

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Stripp, S.T. Bonds from bands. Nat Rev Chem 5, 146–147 (2021). https://doi.org/10.1038/s41570-021-00256-7

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