High-temperature (high-Tc) superconductivity in cuprates arises from carrier doping of an antiferromagnetic Mott insulator. This carrier doping leads to the formation of electronic liquid-crystal phases1. The insulating charge-stripe crystal phase is predicted to form when a small density of holes is doped into the charge-transfer insulator state1,2,3, but this phase is yet to be observed experimentally. Here, we use surface annealing to extend the accessible doping range in Bi-based cuprates and realize the lightly doped charge-transfer insulating state of the cuprate Bi2Sr2CaCu2O8+x. In this insulating state with a charge transfer gap on the order of ~1 eV, our spectroscopic imaging scanning tunnelling microscopy measurements provide strong evidence for a unidirectional charge-stripe order with a commensurate 4a0 period along the Cu–O–Cu bond. Notably, this insulating charge-stripe crystal phase develops before the onset of the pseudogap and formation of the Fermi surface. Our work provides fresh insight into the microscopic origin of electronic inhomogeneity in high-Tc cuprates.
Access optionsAccess options
Subscribe to Journal
Get full journal access for 1 year
only $16.58 per issue
All prices are NET prices.
VAT will be added later in the checkout.
Rent or Buy article
Get time limited or full article access on ReadCube.
All prices are NET prices.
The data supporting the findings of this study are available upon request from the corresponding author.
Kivelson, S. A., Fradkin, E. & Emery, V. J. Electronic liquid-crystal phases of a doped Mott insulator. Nature 393, 550–553 (1998).
Zaanen, J. & Gunnarsson, O. Charged magnetic domain lines and the magnetism of high-T c oxides. Phys. Rev. B 40, 7391–7394 (1989).
Löw, U., Emery, V. J., Fabricius, K. & Kivelson, S. A. Study of an Ising model with competing long- and short-range interactions. Phys. Rev. Lett. 72, 1918–1921 (1994).
Kivelson, S. A. et al. How to detect fluctuating stripes in the high-temperature superconductors. Rev. Mod. Phys. 75, 1201–1241 (2003).
Tranquada, J. M., Sternlieb, B. J., Axe, J. D., Nakamura, Y. & Uchida, S. Evidence for stripe correlations of spins and holes in copper oxide superconductors. Nature 375, 561–563 (1995).
Wu, T. et al. Magnetic-field-induced charge-stripe order in the high-temperature superconductor YBa2Cu3Oy. Nature 477, 191–194 (2011).
Abbamonte, P. et al. Spatially modulated ‘Mottness’ in La2-xBaxCuO4. Nat. Phys. 1, 155–158 (2005).
Ghiringhelli, G. et al. Long-range incommensurate charge fluctuations in (Y,Nd)Ba2Cu3O6+x. Science 337, 821–825 (2012).
Comin, R. et al. Broken translational and rotational symmetry via charge stripe order in underdoped YBa2Cu3O6+y. Science 347, 1335–1339 (2015).
Howald, C., Eisaki, H., Kaneko, N. & Kapitulnik, A. Coexistence of periodic modulation of quasiparticle states and superconductivity in Bi2Sr2CaCu2O8+δ. Proc. Natl Acad. Sci. USA 100, 9705–9709 (2003).
Vershinin, M. et al. Local ordering in the pseudogap state of the high-T c superconductor Bi2Sr2CaCu2O8+δ. Science 303, 1995–1998 (2004).
Comin, R. et al. Charge order driven by Fermi-arc instability in Bi2Sr2−xLaxCuO6+δ. Science 343, 390–392 (2014).
Cai, P. et al. Visualizing the evolution from the Mott insulator to a charge-ordered insulator in lightly doped cuprates. Nat. Phys. 12, 1047–1051 (2016).
Mesaros, A. et al. Commensurate 4a 0-period charge density modulations throughout the Bi2Sr2CaCu2O8+x pseudogap regime. Proc. Natl Acad. Sci. USA 113, 12661–12666 (2016).
Lawler, M. J. et al. Intra-unit-cell electronic nematicity of the high-T c copper-oxide pseudogap states. Nature 466, 347–351 (2010).
Wise, W. D. et al. Charge-density-wave origin of cuprate checkerboard visualized by scanning tunnelling microscopy. Nat. Phys. 4, 696–699 (2008).
Hanaguri, T. et al. A ‘checkerboard’ electronic crystal state in lightly hole-doped Ca2-xNaxCuO2Cl2. Nature 430, 1001–1005 (2004).
Kohsaka, Y. et al. An intrinsic bond-centered electronic glass with unidirectional domains in underdoped cuprates. Science 315, 1380–1385 (2007).
Kohsaka, Y. et al. How Cooper pairs vanish approaching the Mott insulator in Bi2Sr2CaCu2O8+δ. Nature 454, 1072–1078 (2008).
Parker, C. V. et al. Fluctuating stripes at the onset of the pseudogap in the high-T c superconductor Bi2Sr2CaCu2O8+x. Nature 468, 677–680 (2010).
Kohsaka, Y. et al. Visualization of the emergence of the pseudogap state and the evolution to superconductivity in a lightly hole-doped Mott insulator. Nat. Phys. 8, 534–538 (2012).
Fujita, K. et al. Simultaneous transitions in cuprate momentum-space topology and electronic symmetry breaking. Science 344, 612–616 (2014).
da Silva Neto, E. H. et al. Ubiquitous interplay between charge ordering and high-temperature superconductivity in cuprates. Science 343, 393–396 (2014).
Ruan, W. et al. Relationship between the parent charge transfer gap and maximum transition temperature in cuprates. Sci. Bull. 61, 1826–1832 (2016).
Pan, S.-H. et al. Microscopic electronic inhomogeneity in the high-T c superconductor Bi2Sr2CaCu2O8+x. Nature 413, 282–285 (2001).
Lang, K. M. et al. Imaging the granular structure of high-T c superconductivity in underdoped Bi2Sr2CaCu2O8+δ. Nature 415, 412–416 (2002).
McElroy, K. et al. Atomic-scale sources and mechanism of nanoscale electronic disorder in Bi2Sr2CaCu2O8+δ. Science 309, 1048–1052 (2005).
Zeljkovic, I. et al. Imaging the impact of single oxygen atoms on superconducting Bi2+ySr2-yCaCu2O8+x. Science 337, 320–323 (2012).
Zhou, S., Ding, H. & Wang, Z. Correlating off-stoichiometric doping and nanoscale electronic inhomogeneity in the high-T c superconductor Bi2Sr2CaCu2O8+δ. Phys. Rev. Lett. 98, 076401 (2007).
Mitzi, D. B., Lombardo, L. W., Kapitulnik, A., Laderman, S. S. & Jacowitz, R. D. Growth and properties of oxygen- and ion-doped Bi2Sr2CaCu2O8+δ single crystals. Phys. Rev. B 41, 6564–6574 (1990).
Fradkin, E., Kivelson, S. A. & Tranquada, J. M. Colloquium: Theory of intertwined orders in high temperature superconductors. Rev. Mod. Phys. 87, 457–482 (2015).
Wang, Y. & Chubukov, A. V. Interplay between unidirectional and bidirectional charge-density-wave orders in underdoped cuprates. Phys. Rev. B 92, 245140 (2015).
Arrigoni, E., Fradkin, E. & Kivelson, S. A. Mechanism of high-temperature superconductivity in a striped Hubbard model. Phys. Rev. B 69, 214519 (2004).
Huang, E. W. et al. Numerical evidence of fluctuating stripes in the normal state of high-T c cuprate superconductors. Science 358, 1161–1164 (2017).
Tranquada, J. M., Buttrey, D. J., Sachan, V. & Lorenzo, J. E. Simultaneous ordering of holes and spins in La2NiO4.125. Phys. Rev. Lett. 73, 1003–1006 (1994).
Comin, R. & Damascelli, A. Resonant X-ray scattering studies of charge order in cuprates. Annu. Rev. Condens. Matter Phys. 7, 369–405 (2016).
The authors thank M. Allan, J.C. Davis, J.E. Hoffman, S. Kivelson and S. Sachdev for insightful conversations. I.Z. acknowledges support from DARPA grant no. N66001-17-1-4051 (Z.R.), Army Research Office grant no. W911NF-17-1-0399 (B.R.), National Science Foundation grant no. NSF-DMR-1654041 (H.Z.) and the Boston College startup. Z.W. acknowledges support from the US Department of Energy, Basic Energy Sciences grant no. DE-FG02-99ER45747. The work in Brookhaven was supported by the Office of Science, US Department of Energy under contract no. DE-SC0012704. J.S. and R.Z. were supported by the Center for Emergent Superconductivity, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science.
The authors declare no competing interests.
Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Sections 1–8, Supplementary Figures 1–11, Supplementary References 1–16
About this article
Is There Any Hidden Symmetry in the Stripe Structure of Perovskite High-Temperature Superconductors?
The Journal of Physical Chemistry Letters (2019)
Physical Review X (2019)