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Interphase identity crisis

Interphases that form on the anode surface of lithium-ion batteries are critical for performance and lifetime, but are poorly understood. Now, a decade-old misconception regarding a main component of the interphase has been revealed, which could potentially lead to improved devices.

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Fig. 1: Lithium ethylene monocarbonate in the solid–electrolyte interphase.


  1. Xu, K. Chem. Rev. 114, 11503–11618 (2014).

    Article  CAS  Google Scholar 

  2. Aurbach, D., Markovsky, B., Shechter, A., Ein-Eli, Y. & Cohen, H. J. Electrochem. Soc. 143, 3809–3820 (1996).

    Article  CAS  Google Scholar 

  3. Wang, L. et al. Nat. Chem. (2019).

  4. Gireaud, L., Grugeon, S., Laruelle, S., Pilard, S. & Tarascon, J.-M. J. Electrochem. Soc. 152, A850–A857 (2005).

    Article  CAS  Google Scholar 

  5. Borodin, O., Smith, G. D. & Fan, P. J. Phys. Chem. B 110, 22773–22779 (2006).

    Article  CAS  Google Scholar 

  6. Janek, J. & Zeier, W. G. Nat. Energy 1, 16141 (2016).

    Article  Google Scholar 

  7. Gachot, G. et al. J. Power Sources 178, 409–421 (2008).

    Article  CAS  Google Scholar 

Download references

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Correspondence to Stefan A. Freunberger.

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Freunberger, S.A. Interphase identity crisis. Nat. Chem. 11, 761–763 (2019).

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