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Development of chiral functional materials based on natural chiral compounds

Polymer Journal volume 54, pages 1161–1169 (2022)Cite this article

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Abstract

Optically active polymers and supramolecules that form well-defined assemblies and architectures are important materials with a wide range of applications. Among the variety of chiral building blocks for the preparation of optically active functional materials, amino acids and sugars stand out because of their versatile structures and functional groups. In these chiral units, intra- and intermolecular noncovalent interactions, such as hydrogen bonding and π-stacking, play significant roles in the generation of smart functions. This review summarizes the fabrication and functions of chiral conjugated polyacetylenes and polyarylene ethynylenes and chiral supramolecules based on these natural chiral compounds.

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Acknowledgements

The author deeply appreciates the encouragement and meaningful discussions of Prof. Fumio Sanda (Kansai University), Prof. Toshikazu Takata (Hiroshima University) and Prof. Keiji Numata (Kyoto University) throughout his study. The author would also like to express his appreciation to all his colleagues for their valuable contributions to this focus review.

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  1. Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, 3-3-35 Yamate-cho, Suita, Osaka, 564-8680, Japan

    Hiromitsu Sogawa

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  1. Hiromitsu Sogawa
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Correspondence to Hiromitsu Sogawa.

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Sogawa, H. Development of chiral functional materials based on natural chiral compounds. Polym J 54, 1161–1169 (2022). https://doi.org/10.1038/s41428-022-00677-1

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