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Fabrication of single-ion conducting polymer-coated separators and their application in nonaqueous Li-O2 batteries

Polymer Journal volume 53, pages 549–556 (2021)Cite this article

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Abstract

Nonaqueous lithium-oxygen (Li-O2) batteries have attracted increasing attention as potential candidates for next-generation batteries due to their significantly high theoretical energy densities. However, they are still in their infancy due to numerous problems. In this study, a cross-linked single-ion conducting polymer network with a highly delocalized anionic group was coated onto a thin commercial polyethylene membrane separator via a facile UV polymerization method. The resulting polymer coating improves the electrolyte wettability and suppresses the diffusion of anionic species across the separator. The effect of the polymer modification of the separator on the electrochemical properties of nonaqueous Li-O2 cells was investigated.

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Acknowledgements

This work was supported in part by the Iketani Science and Technology Foundation and Grants-in-Aid for Scientific Research (No. 20K15349 to RT) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. This work also received support from the National Institute for Materials Science (NIMS) Battery Research Platform. PP and KS are indebted to the NIMS Internship Program.

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Authors and Affiliations

  1. Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan

    Peeranuch Poungsripong, Ryota Tamate, Manai Ono, Ken Sakaushi & Makoto Ue

  2. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, 10330, Thailand

    Peeranuch Poungsripong

  3. NIMS-SoftBank Advanced Technologies Development Center, National Institute for Material Science, 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan

    Ryota Tamate & Ken Sakaushi

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  1. Peeranuch Poungsripong
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Correspondence to Ryota Tamate.

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Poungsripong, P., Tamate, R., Ono, M. et al. Fabrication of single-ion conducting polymer-coated separators and their application in nonaqueous Li-O2 batteries. Polym J 53, 549–556 (2021). https://doi.org/10.1038/s41428-020-00449-9

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