Abstract
Interfacial polycondensation of cyclohexanedicarbonyl dichlorides and adamantanedicarbonyl dichloride with bisphenols in 2 M NaOH aq./CHCl3 afforded semi-aromatic polyesters. Glass transition temperatures (Tg’s) of the resulting polyesters are in the range of 110–222 °C. Temperatures where 5% weight losses of the polyesters occur in N2 are in the range of 304–448 °C. Polyesters 4 and 10, which include trans-1,2-cyclohexanediyl and 1,3-adamantanadicarbonyl units, respectively, have excellent solubility in organic solvents. The polyester films 10a,b,e, which are prepared by casting from CHCl3, have excellent transparency.
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Maeyama, K., Akiba, K. & Saito, H. Facile Syntheses of Aromatic Polyesters Bearing Alicyclic Units in the Main Chains. Polym J 40, 629–633 (2008). https://doi.org/10.1295/polymj.PJ2008065
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DOI: https://doi.org/10.1295/polymj.PJ2008065