Abstract
Organic–inorganic polymer hybrids having IPN (Interpenetrating Polymer Network) structure were synthesized utilizing an in-situ method, which was the simultaneous formation of organic gel through metal–bipyridyl complex and silica gel. Metal–bipyridyl complex was used as a cross-linking point to prepare the organic gel. The properties of the polymer hybrids, such as solvent-resistant and thermal properties, were different according to the kinds and the weight of the used metal ions. Especially, thermo-responsive polymer hybrids could be obtained using iron (II)–bipyridyl complex as a cross-linking point in the silica matrix.
Similar content being viewed by others
Article PDF
References
B. M. Novak, Adv. Mater., 5, 442 (1993).
U. Schubert, N. Husing, and A. Lorenz, Chem. Mater., 7, 2010 (1995).
P. Judeinstein and C. Sanchez, J. Mater. Chem., 6, 511 (1996).
J. Wei and G. L. Wilkes, Chem. Mater., 8, 1667 (1996).
Y. Chujo, Curr. Opin. Solid State Mater. Eng., 1, 806 (1996).
C. F. Bohren and D. R. Huffman, “Absorption and Scattering of Light by Small Particles,” Wiley, New York, N.Y., 1983, p 3.
Y. Chujo, S. Kure, H. Matsuki, T. Saegusa, and T. Yazawa, Polym. Prep. Jpn., 42, 839 (1993).
R. Tamaki, Y. Chujo, K. Kuraoka, and T. Yazawa, J. Mater. Chem., 8, 1741 (1999).
C. J. Brinker and G. W. Scherer, “Sol-Gel Science, The Physics and Chemistry of Sol-Gel Processing,” Academic Press Inc., San Diego, CA, 1990, p 97.
H.-H. Huang, B. Orler, and G. L. Wilkes, Macromolecules, 20, 1322 (1987).
Y. Wei, D. Yang, L. Tang, and M. K. Hutchins, J. Mater. Res., 8, 1143 (1993).
Y. Wei, J.-M. Yeh, X. Jia, and J. Wang, Chem. Mater., 7, 969 (1995).
Y. Chujo and T. Saegusa, Adv. Polym. Sci., 100, 11 (1992).
T. Saegusa and Y. Chujo, Makromol. Chem., Macromol. Symp., 51, 1 (1991).
Y. Chujo, H. Matsuki, S. Kure, T. Saegusa, and T. Yazawa, J. Chem. Soc., Chem. Commun., 635 (1994).
R. Tamaki, K. Samura, and Y. Chujo, Chem. Commun., 1131 (1998).
R. Tamaki and Y. Chujo, Chem. Mater., 7, 1719 (1999).
R. Tamaki, K. Naka, and Y. Chujo, Polym. Bull., 39, 303 (1997).
T. Ogoshi, H. Itoh, K. M. Kim, and Y. Chujo, Macromolecules, 35, 334 (2002).
M. Schroder and T. A. Stephenson, “Comprehensive Coordination Chemistry”, G. Wilkinson, Ed., Pergamon Press, New York, N.Y., 1987, vol. 4, p 215.
F. Basolo, J. C. Hayes, and H. M. Neumann, J. Am. Chem. Soc., 75, 5102 (1953).
F. Basolo, J. C. Hayes, and H. M. Neumann, J. Am. Chem. Soc., 76, 3807 (1954).
Y. Chujo, K. Sada, and T. Saegusa, Macromolecules, 24, 6315 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ogoshi, T., Itoh, H., Kim, KM. et al. Thermal and Solvent-Resistant Properties of Organic–Inorganic Polymer Hybrids Having Interpenetrating Polymer Network Structure by Formation of Metal–Bipyridyl Complex. Polym J 35, 178–184 (2003). https://doi.org/10.1295/polymj.35.178
Issue Date:
DOI: https://doi.org/10.1295/polymj.35.178