Abstract
A series of fluorine-containing oligomeric nonionic surfactants consisting of a perfluoroacyl group as the hydrophobic group and poly[(N-acetylimino)ethylene] as the hydrophilic group was prepared by the cationic ring-opening oligomerization of 2-methyl-2-oxazoline initiated by a 1:1 adduct of 2-(perfluoroalkyl)-2-oxazoline with methyl trifluoromethanesulfonate or p-toluenesulfonate. The degree of polymerization of the obtained oligomers was in a range of 1—7. The superior property of these fluorine-containing nonionic surfactants was demonstrated by the measurement of surface tension of their aqueous solutions.
Similar content being viewed by others
Article PDF
References
For example, see M. J. Schick, “Nonionic Surfactant,” Marcel Dekker, Inc., New York, N.Y., 1967.
S. Kobayashi, T. Igarashi, Y. Moriuchi, and T. Saegusa, Macromolecules, 19, 535 (1986).
S. Kobayashi, M. Kaku, and T. Saegusa, Macromolecules, 21, 334 (1988).
S. Kobayashi, H. Uyama, E. Ihara, and T. Saegusa, Macromolecules, 23, 1586 (1990).
S. Kobayashi, H. Uyama, D. R. Liu, and T. Saegusa, Macromolecules, 23, 5075 (1990).
S. Kobayashi, S. Iijima, T. Igarashi, and T. Saegusa, Macromolecules, 20, 1729 (1987).
M. H. Litt, T. T. Chen, and B. R. Hsieh, J. Polym. Sci., Polym. Chem., 24, 3407 (1986).
M. H. Litt, B. R. Hsieh, I. M. Krieger, T. T. Chen, and H. L. Lu, J. Colloid Interface Sci., 115, 312 (1987).
M. Miyamoto, K. Aoi, and T. Saegusa, Macromolecules, 22, 3540 (1989).
S. Kobayashi, H. Uyama, N. Higuchi, and T. Saegusa, Macromolecules, 23, 54 (1990).
M. Miyamoto, Y. Sano, and T. Saegusa, to be submitted to Polym. J.
M. Miyamoto, K. Aoi, and T. Saegusa, Macromolecules, 24, 11 (1991).
H. Lange, in M. J. Schick, “Nonionic Surfactant,” Marcel Dekker, Inc., New York, N. Y., 1967, Chapter 14.
S. Kobayashi, E. Masuda, S. Shoda, and Y. Shimano, Macromolecules, 22, 2878 (1989).
G. H. Hsiue, A. X. Swamikannu, and M. H. Litt, J. Polym. Sci., Polym. Chem. Ed., 26, 3043 (1988).
P. Becher, in M. J. Schick, “Nonionic Surfactant,” Marcel Dekker, Inc., New York, N. Y., 1967, Chapter 15.
M. J. Rosen, J. Colloid Interface Sci., 56, 320 (1976).
E. H. Crook, D. B. Fordyce, and G. F. Trebbi, J. Phys. Chem., 67, 1987 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Miyamoto, M., Yamanaka, H., Aoi, K. et al. Preparation of Poly[(N-acetylimino)ethylene] Having (Perfluoroacylimino)ethyl End Group and Its Surface Activity. Polym J 27, 461–468 (1995). https://doi.org/10.1295/polymj.27.461
Issue Date:
DOI: https://doi.org/10.1295/polymj.27.461