Abstract
Poly(3-vinylperylene) has been prepared by radical polymerization of 3-vinylperylene, and characterized by spectroscopic methods, mol. wt. determination, and differential scanning calorimetry. Electrochemical doping of poly(3-vinylperylene), and characterization and electrical properties of doped polymers have been studied. Electrochemically-doped poly(3-vinylperylene) is identified as a partially oxidized radical-cation salt with ClO4− as a dopant. The polymer with a doping degree of 86% exhibits a room-temperature conductivity of 1×10−5 S cm−1 and an activation energy of ca. 0.4 eV. The presence of hole charge carriers is shown from the electron spin resonance spectrum.
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Jeon, IR., Noma, N., Claridge, R. et al. Electrochemical Doping of Poly(3-vinylperylene) and Electrical Properties of Doped Polymers. Polym J 24, 273–279 (1992). https://doi.org/10.1295/polymj.24.273
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DOI: https://doi.org/10.1295/polymj.24.273