Abstract
A series of comb-like polymers, poly(2-alkyltrimethylene alkanedioates), were synthesized from 2-dodecyl-, 2-tetradecyl-, 2-hexadecyl-, or 2-octadecylpropanediol-1,3 and sebacoyl, tetradecanedioyl, octadecanedioyl or henicosanedioyl chloride. A differential scanning calorimetry study on the crystallization of these more widely spaced comb-like polymers showed that crystallization involves the main-chains as well as side-chains.
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Hirabayashi, T., Kasabou, K. & Yokota, K. More Widely Spaced Comb-Like Polymers of Which Teeth Appear on Every 15, 19, 23, and 26 Repeating Main-Chain Atoms. Polym J 20, 911–917 (1988). https://doi.org/10.1295/polymj.20.911
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DOI: https://doi.org/10.1295/polymj.20.911