Abstract
The structure-conductivity relationships were investigated on the network polymers from poly(ethylene oxide)(PEO) containing lithium perchlorate (LiClO4), in contrast to the polymer complex formed by linear PEO and LiClO4. The crosslinked structure caused a considerable decrease in the degree of the crystallinity of the resulting PEO–LiClO4 complexes, which contributed to high ionic conductivity. Li+ ions were demonstrated as mobile species in these polymer complexes, while ClO4− ions contributed somewhat to ionic conductivity. The high ionic conductivity of the order of 10−5 Scm1 at 30°C was attained by a crosslinked PEO–LiClO4 complex of [LiClO4]/[EO unit] =0.02.
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Watanabe, M., Nagano, S., Sanui, K. et al. Ionic Conductivity of Network Polymers from Poly(ethylene oxide) Containing Lithium Perchlorate. Polym J 18, 809–817 (1986). https://doi.org/10.1295/polymj.18.809
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DOI: https://doi.org/10.1295/polymj.18.809
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