Abstract
Copolymerization of acetylenic donor and acceptor monomers catalyzed by ethylaluminum chloride with or without transition metal compounds was investigated. The addition of a transition metal compound increases the yield and the molecular weight of a copolymer, but has little effect on the copolymer composition. The resulting copolymers were each found to possess an almost 1:1 composition, but a relatively low molecular weight.
Similar content being viewed by others
Article PDF
References
M. Hatano, S. Kambara, and S. Okamoto, J. Polym. Sci., 51, S26 (1961).
H. Shirakawa, T. Ito, and S. Ikeda, Polym. J., 4, 460 (1973).
T. Masuda, T. Kim-Quan, and T. Higashimura, Polym. J., 10, 269 (1978).
Cr. Simionescu, S. Dumitrescu, and V. Percec, Polym. J., 8, 139 (1976).
H. Noguchi and S. Kambara, J. Polym. Sci., B, 1, 553 (1963).
as a review, M. G. Chanser, Usp. Khim., 45, 695 (1976).
A. G. Hankin and A. M. North, Trans. Faraday Soc., 63, 1525 (1967).
L. S. Meriwether, E. C. Colthup, G. W. Kennerly, and R. N. Reusch, J. Org. Chem., 26, 5155 (1961).
J. Furukawa, E. Kobayashi, and T. Kawagoe, J. Polym. Sci., Polym. Chem. Ed., 14, 1609 (1978).
C. H. Moureu and J. Ch. Bongrand, Ann. Chim., 14, 47 (1920).
T. Masuda, T. Ohtori, T. Mouri, and T. Higashimura, Polym. Prepr., Jpn., 27, 773 (1978).
P. Ehrlich, J. Macromol. Sci., Phys., B 2, 153 (1968).
G. M. Holob, P. Ehrlich, and R. D. Allendoerfer, Macromolecules, 5, 569 (1972).
H. Shirakawa, T. Sakaki, and S. Ikeda, Chem. Lett., 1113 (1978).
J. Furukawa and E. Kobayashi, Rubber Chem. Technol., 51, 600 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Furukawa, J., Kobayashi, E. & Wakui, T. Alternating Copolymerization of Acetylenic Donor and Acceptor Monomers. Polym J 12, 17–23 (1980). https://doi.org/10.1295/polymj.12.17
Issue Date:
DOI: https://doi.org/10.1295/polymj.12.17
Keywords
This article is cited by
-
Electrochemically initiated copolymerization of some acetylenic derivatives
Polymer Bulletin (1981)