Abstract
With the catalyst system, Co(acac)3–AlEt3–H2O, cis-1,4–1,2-equimolar binary polybutadiene was obtained. The gas-chromatographic analysis of the ozonolysis product of the polymers showed that the sequence distribution was of the random but not alternating type. The preference of microstructure in polymerization is discussed briefly under the consideration of monomer coordination on the catalyst complex and the stability of the growing chain-end.
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Furukawa, J., Haga, K., Kobayashi, E. et al. cis-Vinyl-1:1 Polymer of Butadiene. Polym J 2, 371–378 (1971). https://doi.org/10.1295/polymj.2.371
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DOI: https://doi.org/10.1295/polymj.2.371