Abstract
IT is becoming increasingly clear that a substantial number of solid compounds have ionic conductivities in the range more commonly associated with molten salts. In these solids the ions of one type have diffusivities in the range characteristic of liquids (1 to 10 × 10−9 m2 s1) and specific conductances in the range to 10 to 103 Ω1 m−1 (ref. 1). It is usual and appropriate to refer to such materials as solid electrolytes.
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References
O'Keeffe, M., Fast Ion Transport in Solids (edit, by van Gool, W.), 233 (North-Holland, Amsterdam, 1973).
Nagel, L. E., and O'Keeffe, M., Fast Ion Transport in Solids (edit, by van Gool, W.), 165 (North-Holland, Amsterdam, 1973).
O'Keeffe, M., Science, N.Y., 180, 1276 (1973).
Faraday, M., Experimental Researches in Electricity I, article 1340 (Taylor and Francis, London, 1839).
Tubandt, C., Z. anorg. allg. Chem., 115, 105 (1921).
Schoonman, J., Dirksen, G. J., and Blasse, G., J. Solid St. Chem., 7, 245 (1973).
Schumann, H., Centr. Mineral. Geol., A122 (1933).
Winterhager, H., and Werner, L., Forschungsber. Wirtsch. Verkehrsministeriums Nordrhein-Westfalen, No. 438 (1957).
Adda, Y., and Philibert, J., La Diffusion dans les Solides (Presses Universitaires de France, Paris, 1966).
Axe, J. D., Gablianello, J. W., and Scardefield, J. E., Phys. Rev., 139, A1211 (1965).
Blanc, M., and Petit, G., C.r. hebd. Séanc. Acad. Sci. Paris, 248, 1305 (1959).
Janz, G. J., Molten Salts Handbook (Academic Press, New York, 1967).
de Vries, K. J., and van Santen, J. F., Physica, 29, 482 (1963).
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DERRINGTON, C., O'KEEFFE, M. Anion Conductivity and Disorder in Lead Fluoride. Nature Physical Science 246, 44–46 (1973). https://doi.org/10.1038/physci246044a0
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DOI: https://doi.org/10.1038/physci246044a0
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