Abstract
PERIODIC temperature changes in Belousov-Zhabotinsky type oscillating chemical reactions have been reported; according to Franck and Geiseler1 the temperature fluctuation in one cycle may be as great as 1° C. Busse2 observed a temperature oscillation of about 0.04° C around a nearly constant value and concluded that there was almost no overall heat production in the reaction. He presumed that the chemical energy within one cycle was converted to mechanical energy associated with the formation of carbon dioxide.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
We are sorry, but there is no personal subscription option available for your country.
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Franck, U., & Geiseler, W., Naturwissensch., 58, 52 (1970)
Busse, H. G., Nature Physical Science, 233, 137 (1971).
Belousov, B. P., Shorn. Referat. Radiais. Med. za 1958 (Medgiz, Moscow, 1959).
Zhabotinsky, A. M., Biofizika, 9, 306 (1964).
Zhabotinsky, A. M., Dokl. Akad. Nauk SSSR, 157, 392 (1964).
Noyes, R. M., Field, R. J., & Körös, E., J. Amer. Chem. Soc., 94, 1394 (1972).
Field, R. J., Körös, E., & Noyes, R. M., J. Amer. Chem. Soc., 94, 8649 (1972).
Degn, H., Nature, 213, 589 (1967).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
KŐRÖS, E., ORBÁN, M. & NAGY, Z. Periodic Heat Evolution during Temporal Chemical Oscillations. Nature Physical Science 242, 30–31 (1973). https://doi.org/10.1038/physci242030a0
Received:
Issue Date:
DOI: https://doi.org/10.1038/physci242030a0
This article is cited by
-
Calorimetric study of the BrO 3 − /Ce4+/cyclohexanone and BrO 3 − /Ce4+/cyclopentanone oscillating systems
Reaction Kinetics and Catalysis Letters (1981)
-
Uncatalysed oscillatory chemical reactions
Nature (1978)
-
‘Spatial oscillations’ in the Zhabotinskii reaction
Nature (1974)
-
Monomolecular treatment of chemical oscillation
Nature (1974)
-
The Ru(dipy) 3 2+ -Bromate-Malonic acid oscillating system
Reaction Kinetics and Catalysis Letters (1974)