Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letters to Editor
  • Published:

Periodic Heat Evolution during Temporal Chemical Oscillations

Abstract

PERIODIC temperature changes in Belousov-Zhabotinsky type oscillating chemical reactions have been reported; according to Franck and Geiseler1 the temperature fluctuation in one cycle may be as great as 1° C. Busse2 observed a temperature oscillation of about 0.04° C around a nearly constant value and concluded that there was almost no overall heat production in the reaction. He presumed that the chemical energy within one cycle was converted to mechanical energy associated with the formation of carbon dioxide.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

References

  1. Franck, U., & Geiseler, W., Naturwissensch., 58, 52 (1970)

    Article  ADS  Google Scholar 

  2. Busse, H. G., Nature Physical Science, 233, 137 (1971).

    Article  ADS  Google Scholar 

  3. Belousov, B. P., Shorn. Referat. Radiais. Med. za 1958 (Medgiz, Moscow, 1959).

  4. Zhabotinsky, A. M., Biofizika, 9, 306 (1964).

    Google Scholar 

  5. Zhabotinsky, A. M., Dokl. Akad. Nauk SSSR, 157, 392 (1964).

    Google Scholar 

  6. Noyes, R. M., Field, R. J., & Körös, E., J. Amer. Chem. Soc., 94, 1394 (1972).

    Article  Google Scholar 

  7. Field, R. J., Körös, E., & Noyes, R. M., J. Amer. Chem. Soc., 94, 8649 (1972).

    Article  Google Scholar 

  8. Degn, H., Nature, 213, 589 (1967).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

KŐRÖS, E., ORBÁN, M. & NAGY, Z. Periodic Heat Evolution during Temporal Chemical Oscillations. Nature Physical Science 242, 30–31 (1973). https://doi.org/10.1038/physci242030a0

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1038/physci242030a0

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing