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Hedvall Effect in Cement Chemistry

Abstract

THE increased reactivity of a solid during and as a consequence of a crystalline transformation is commonly known as the Hedvall effect1–3. In a wider sense this effect may include increased reactivity near a transition point. The typical data quoted in support of the Hedvall effect refer to reactions in the binary systems containing silver salts with BaO, SrO and CaO yielding the reciprocal pairs4–7.

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References

  1. Hedvall, J. A., Einführung in die Festköperchemie (Vieweg, Braunschweig, 1952).

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  2. Hauffe, K., Reaktionen in und an Festen Stoffen, 628 (Springer, Berlin, 1955).

  3. Garner, W. E., Chemistry of the Solid State, 309 (Butterworths, London, 1955).

  4. Cohen, G., Chem. Rev., 42, 527 (1948).

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  5. Gray, J., The Defect Solid State, 127 (Interscience, New York, 1957).

  6. Rees, A. L. G., Chemistry of the Defect Solid State, 91 (Methuen, London 1954).

  7. Borchardt, H. J., and Thompson, B. A., J. Amer. Chem. Soc., 82, 5630 (1960).

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  8. Ramachandran, V. S., J. Thermal Analysis, 3, 181 (1971).

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  9. Tenoutasse, N., Manifestations Thermiques de l'Hydration (Colloquium), 10 (Paris, 1969).

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RAMACHANDRAN, V., SEREDA, P. Hedvall Effect in Cement Chemistry. Nature Physical Science 233, 134–135 (1971). https://doi.org/10.1038/physci233134a0

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