Consistent thermostatistics forbids negative absolute temperatures

Abstract

Over the past 60 years, a considerable number of theories and experiments have claimed the existence of negative absolute temperature in spin systems and ultracold quantum gases. This has led to speculation that ultracold gases may be dark-energy analogues and also suggests the feasibility of heat engines with efficiencies larger than one. Here, we prove that all previous negative temperature claims and their implications are invalid as they arise from the use of an entropy definition that is inconsistent both mathematically and thermodynamically. We show that the underlying conceptual deficiencies can be overcome if one adopts a microcanonical entropy functional originally derived by Gibbs. The resulting thermodynamic framework is self-consistent and implies that absolute temperature remains positive even for systems with a bounded spectrum. In addition, we propose a minimal quantum thermometer that can be implemented with available experimental techniques.

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Figure 1: Non-negativity of the absolute temperature in quantum systems with a bounded spectrum.

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Acknowledgements

We thank I. Bloch, W. Hofstetter and U. Schneider for constructive discussions. We are grateful to M. Campisi for pointing out equation (14), and to P. Kopietz, P. Talkner, R. E. Goldstein and, in particular, P. Hänggi for helpful comments.

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Correspondence to Jörn Dunkel.

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Dunkel, J., Hilbert, S. Consistent thermostatistics forbids negative absolute temperatures. Nature Phys 10, 67–72 (2014). https://doi.org/10.1038/nphys2815

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