Abstract
Many creatures in nature, such as butterflies and peacocks, display unique brilliant colours, known as ‘structural colours’, which result from the interaction of light with periodic nanostructures on their surfaces. Mimicking such nanostructures found in nature, however, requires state-of-the-art nanofabrication techniques that are slow, expensive and not scalable. Herein, we demonstrate high-resolution patterning of multiple structural colours within seconds, based on successive tuning and fixing of colour using a single material along with a maskless lithography system. We have invented a material called ‘M-Ink’, the colour of which is tunable by magnetically changing the periodicity of the nanostructure and fixable by photochemically immobilizing those structures in a polymer network. We also demonstrate a flexible photonic crystal for the realization of structural colour printing. The simple, controllable and scalable structural colour printing scheme presented may have a significant impact on colour production for general consumer goods.
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References
Srinivasarao, M. Nano-optics in the biological world: beetles, butterflies, birds and moths. Chem. Rev. 99, 1935–1961 (1999).
Vukusic, P., Sambles, J. R. & Lawrence, C. R. Colour mixing in wing scales of a butterfly. Nature 404, 457 (2000).
Parker, A. R., McPhedran, R. C., Mckenzie, D. R., Botten, L. C. & Nicorovici, N. P. Aphrodite's iridescence. Nature 409, 36–37 (2001).
Kinoshita, S., Yoshioka, S. & Kawagoe, K. Mechanisms of structural colour in the Morpho butterfly: cooperation of regularity and irregularity in an iridescent scale. Proc. R. Soc. B 269, 1417–1421 (2002).
Zi, J. et al. Coloration strategies in peacock feathers. Proc. Natl Acad. Sci. USA 100, 12576–12578 (2003).
Potyrailo, R. A. et al. Morpho butterfly wing scales demonstrate highly selective vapour response. Nature Photon. 1, 123–128 (2007).
Braun, P. V. et al. Epitaxial growth of high dielectric contrast three-dimensional photonic crystals. Adv. Mater. 13, 721–724 (2001).
Lee, S., Yi, G. & Yang, S. High-speed fabrication of patterned colloidal photonic structures in centrifugal microfluidic chips. Lab. Chip 6, 1171–1177 (2006).
Lu, Y., Yin, Y., Gates, B. & Xia, Y. Growth of large crystals of monodispersed spherical colloids in fluidic cells fabricated using non-photolithographic methods. Langmuir 17, 6344–6350 (2001).
Holgado, M. et al. Electrophoretic deposition to control artificial opal growth. Langmuir 15, 4701–4704 (1999).
Jiang, P., Bertone, J. F., Hwang, K. S. & Colvin, V. L. Single-crystal colloidal multilayers of controlled thickness. Chem. Mater. 11, 2132–2140 (1999).
Velev, O. D., Lenhoff, A. M. & Kaler, E. W. A class of microstructured particles through colloidal crystallization. Science 287, 2240–2243 (2000).
Vlasov, Y. A., Bo, X., Sturm, J. C. & Norris, D. J. On-chip natural assembly of silicon photonic bandgap crystals. Nature 414, 289–293 (2001).
Gu, Z., Fujishima, A. & Sato, O. Fabrication of high-quality opal films with controllable thickness. Chem. Mater. 14, 760–765 (2002).
Fudouzi, H. & Xia, Y. Colloidal crystals with tunable colors and their use as photonic papers. Langmuir 19, 9653–9660 (2003).
Prevo, B. G. & Velev, O. D. Controlled, rapid deposition of structured coatings from micro- and nanoparticle suspensions. Langmuir 20, 2099–2107 (2004).
Masuda, Y., Itoh, T., Itoh, M. & Koumoto, K. Self-assembly patterning of colloidal crystals constructed from opal structure or NaCl structure. Langmuir 20, 5588–5592 (2004).
Wang, J. et al. Simple fabrication of full color colloidal crystal films with tough mechanical strength. Macromol. Chem. Phys. 207, 596–604 (2006).
Arsenault, A. C. et al. From colour fingerprinting to the control of photoluminescence in elastic photonic crystals. Nature Mater. 5, 179–184 (2006).
Arsenault A. C. et al. Photonic-crystal full-colour displays. Nature Photon. 1, 468–472 (2007).
Huang, J., Wang, X. & Wang, Z. L. Controlled replication of butterfly wings for achieving tunable photonic properties. Nano Lett. 6, 2325–2331 (2006).
Saito, A., Yoshioka, S. & Kinoshita, S. Reproduction of the Morpho butterfly's blue: arbitration of contradicting factors. Proc. SPIE 5526, 188–194 (2004).
Wong, T., Gupta, M. C., Robins, B. & Levendusky, T. L. Color generation in butterfly wings and fabrication of such structures. Opt. Lett. 28, 2342–2344 (2003).
Watanabe, K. et al. Optical measurement and fabrication from a Morpho-butterfly-scale quasistructure by focused ion beam chemical vapor deposition. J. Vac. Sci. Technol. B 23, 570–574 (2005).
Ge, J., Hu, Y. & Yin, Y. Highly tunable superparamagnetic colloidal photonic crystals. Angew Chem. Int. Ed. 46, 7428–7431 (2007).
Ge, J. & Yin, Y. Magnetically tunable colloidal photonic structures in alkanol solutions. Adv. Mater. 20, 3485–3491 (2008).
Furst, E. M. & Gast, A. P. Dynamics and lateral interactions of dipolar chains. Phys. Rev. E 62, 6916–6925 (2000).
Martin, J. E., Hill, K. M. & Tigges, C. P. Magnetic-field-induced optical transmittance in colloidal suspensions. Phys. Rev. E 59, 5676–5692 (1999).
Raghavan, S. R., Walls, H. J. & Khan, S. A. Rheology of silica dispersions in organic liquids: new evidence for solvation forces dictated by hydrogen bonding. Langmuir 16, 7920–7930 (2000).
Kobayashi, M., Juillerat, F., Galletto, P., Bowen, P. & Borkovec, M. Aggregation and charging of colloidal silica particles: effect of particle size. Langmuir 21, 5761–5769 (2005).
Dickstein, A. J., Erramilli, S., Goldstein, R. E., Jackson, D. P. & Langer, S. A. Labyrinthine pattern formation in magnetic fluids. Science 261, 1012–1015 (1993).
Panda, P. et al. Stop-flow lithography to generate cell-laden microgel particles. Lab. Chip 8, 1056–1061 (2008).
Chung, S. E. et al. Optofluidic maskless lithography system for real-time synthesis of photopolymerized microstructures in microfluidic channels. Appl. Phys. Lett. 91, 041106 (2007).
Chung, S. E., Park, W., Shin, S., Lee, S. A. & Kwon, S. Guided and fluidic self-assembly of microstructures using railed microfluidic channels. Nature Mater. 7, 581–587 (2008).
Ito, T. & Okazaki, S. Pushing the limits of lithography. Nature 406, 1027–1031 (2000).
Bayer, B. E. An optimum method for two-level rendition of continuous-tone pictures. Proc. IEEE Int. Conf. Commun. 1, 26-11–26-15 (1973).
Ulichney, R. Digital Halftoning (MIT Press, 1987).
Acknowledgements
This work was partly supported by the System IC 2010 project of the Ministry of Knowledge Economy and the Nano Systems Institute National Core Research Center (NSI-NCRC) programme of KOSEF. We thank S.E. Chung and N.R. Kim of the School of Electrical Engineering and Computer Science, SNU, for experimental advice. Y.Y. thanks the University of California, Riverside for provision of startup support, and also the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research.
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H.K., Y.Y. and S.K. designed the experiment. H.K., J.G., J.K., S.-e.C., Hosuk L., Howon L. and W.P. performed the experiments and analysis.
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Kim, H., Ge, J., Kim, J. et al. Structural colour printing using a magnetically tunable and lithographically fixable photonic crystal. Nature Photon 3, 534–540 (2009). https://doi.org/10.1038/nphoton.2009.141
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DOI: https://doi.org/10.1038/nphoton.2009.141
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