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Macromolecular mixing

Entropic templating

The entropic repulsion between tethered molecular brushes at fluid interfaces templates the mixing of otherwise incompatible macromolecules.

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Figure 1: The repulsive (entropic) interactions between polymer molecules in confined environments are soft- and long-ranged.
Figure 2: Entropic-templated mixing at an interface.

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Correspondence to Igal Szleifer.

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Szleifer, I. Entropic templating. Nature Mater 12, 693–694 (2013). https://doi.org/10.1038/nmat3728

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