The accumulation of multiple redox equivalents is essential in photo-driven catalytic reactions such as solar water splitting. However, direct spectroscopic observation of a twice-oxidized species under diffuse illumination has proved elusive until now.
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References
Hammarström, L. Acc. Chem. Res. 48, 840–850 (2015).
Chen, H.-Y. & Ardo, S. Nat. Chem. https://doi.org/10.1038/nchem.2892 (2017).
Faunce, T. A. et al. Energy Environ. Sci. 6, 1074–1076 (2013).
Mann, K. R. et al. J. Am. Chem. Soc. 99, 5525–5526 (1977).
Heyduk, A. F. & Nocera, D. G. Science 293, 1639–1641 (2001).
Moore, G. F. et al. Energy Environ. Sci. 4, 2389–2392 (2011).
Song, W. et al. J. Am. Chem. Soc. 135, 11587–11594 (2013).
Rutherford, A. W. & Moore, T. A. Nature 453, 449 (2008).
Chang, D. W. et al. RSC Adv. 2, 6209–6215 (2012).
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Beiler, A., Moore, G. Caught in the act. Nature Chem 10, 3–4 (2018). https://doi.org/10.1038/nchem.2896
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DOI: https://doi.org/10.1038/nchem.2896