Superatomic solids

Intercalation without altercation

  • A Correction to this article was published on 19 December 2017

Building materials with clusters instead of atoms promises unconventional properties, but those 'superatomic solids' are often too fragile to manipulate. Now, intercalating a guest within an ionic layered solid made of fullerenes and metal chalcogenide clusters greatly alters its conductivity and optical properties without disrupting its crystalline structure.

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Figure 1: Overview of the structural and electronic features of the intercalation of TCNE guests within the {Co6Te8}(C60)3 layered material.

Change history

  • 11 December 2017

    In the News & Views 'Superatomic solids: Intercalation without altercation', in Fig. 1, the crystal structures in panels b and c had been erroneously swapped, this has been corrected after print 11 December 2017.


  1. 1

    Ganin, A. Y. et al. Nature 466, 221–225 (2010).

    CAS  Article  Google Scholar 

  2. 2

    Mandal, S. et al. Acc. Chem. Res. 46, 2385–2395 (2013).

    CAS  Article  Google Scholar 

  3. 3

    O'Brien, E. S. et al. Nat. Chem. 9, 1170–1174 (2017).

    CAS  Article  Google Scholar 

  4. 4

    Khanna, S. N. & Jena, P. Phys. Rev. B 51, 13705–13716 (1995).

    CAS  Article  Google Scholar 

  5. 5

    Knight, W. D. et al. Phys. Rev. Lett. 52, 2141–2143 (1984).

    CAS  Article  Google Scholar 

  6. 6

    Walter, M. et al. Proc. Natl Acad. Sci. USA 105, 9157–9162 (2008).

    CAS  Article  Google Scholar 

  7. 7

    Aikens, C. M. J. Phys. Chem. Lett. 2, 99–104 (2011).

    CAS  Article  Google Scholar 

  8. 8

    Roy, X. et al. Science 341, 157–160 (2013).

    CAS  Article  Google Scholar 

  9. 9

    Chauhan, V., Reber, A. C. & Khanna, S. N. J. Am. Chem. Soc. 139, 1871–1877 (2017).

    CAS  Article  Google Scholar 

  10. 10

    Yu, J. et al. Nano Lett. 16, 3385–3389 (2016).

    CAS  Article  Google Scholar 

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Correspondence to Shiv N. Khanna or Arthur C. Reber.

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Khanna, S., Reber, A. Intercalation without altercation. Nature Chem 9, 1151–1152 (2017).

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