In the version of this Article originally published, a systematic error in converting the energies obtained by molecular mechanics calculations to the total energies used to evaluate the relative stabilities of the molecular network models, led to incorrect energy values being reported. The correct values are as follows:
In 'Control of homochirality in a porous molecular network', modelling of hexamers of cDBA-OC12-( S) CW structure was found to be 9.66 kcal mol−1 more stable than the CCW pattern.
In 'Chiral induction in a porous molecular network', the difference between CW and CCW hexamers formed by five molecules of DBA-OC12 and one of cDBA-OC12-( S) was found to be only 0.24 kcal mol−1.
In 'Hierarchical chiral induction mechanism', for cyclic hexamers of one chiral cDBA-OC12-( S )-OC13-( R) and five achiral DBA-OC12 on graphite, the CW hexagonal structure is favoured by 3.88 kcal mol−1. In comparison, in similar structures made from cDBA-OC12-( S )-OC13-( R) and DBA-OC13 the energy difference between the CW and CCW structures was only 1.33 kcal mol−1.
These errors do not affect the conclusions of the work, and all of the values have been corrected in the online versions of the Article.
Additional information
The online version of the original article can be found at 10.1038/nchem.1111
Rights and permissions
About this article
Cite this article
Tahara, K., Yamaga, H., Ghijsens, E. et al. Erratum: Control and induction of surface-confined homochiral porous molecular networks. Nature Chem 6, 1024 (2014). https://doi.org/10.1038/nchem.2098
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.2098
