Mastering how to completely control the exact monomer sequence of synthetic polymers is the ultimate key for establishing true biomimetic macromolecular chemistry. A versatile one-pot approach for the synthesis of well-defined multiblock copolymers with short block lengths offers another approach on the road towards this lofty goal.
This is a preview of subscription content, access via your institution
Relevant articles
Open Access articles citing this article.
-
The limits of precision monomer placement in chain growth polymerization
Nature Communications Open Access 01 February 2016
Access options
Subscribe to this journal
Receive 12 print issues and online access
$259.00 per year
only $21.58 per issue
Rent or buy this article
Prices vary by article type
from$1.95
to$39.95
Prices may be subject to local taxes which are calculated during checkout
References
Lutz, J.-F., Ouchi, M., Liu, D. R. & Sawamoto, M. Science 341, 1238149 (2013).
Gody, G., Maschmeyer, T., Zetterlund, P. & Perrier, S. Nature Commun. 4, 2505 (2013).
Chiefari, J. et al. Macromolecules 31, 5559–5562 (1998).
Barner-Kowollik, C. (ed.) Handbook of RAFT Polymerization (Wiley-VCH, 2008).
Zamfir, M. & Lutz, J.-F. Nature Commun. 3, 1138 (2012).
Merrifield, R. B. J. Am. Chem. Soc. 85, 2149–2154 (1963).
Niu, J., Hili, R. & Liu, D. R. Nature Chem. 5, 282–292 (2013).
Lewandowski, B. et al. Science 339, 189–193 (2013).
Ida, S., Ouchi, M. & Sawamoto, M. J. Am. Chem. Soc. 132, 14748–14750 (2010).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Schmidt, B., Barner-Kowollik, C. Macromolecules made to order. Nature Chem 5, 990–992 (2013). https://doi.org/10.1038/nchem.1806
Published:
Issue Date:
DOI: https://doi.org/10.1038/nchem.1806
This article is cited by
-
Synthesis and characterization of the block copolymers using the novel bifunctional initiator by RAFT and FRP technics: evaluation of the primary polymerization parameters
Journal of Polymer Research (2020)
-
The limits of precision monomer placement in chain growth polymerization
Nature Communications (2016)
-
Synthesis of pH- and thermo-responsive poly (ε-caprolactone-b-4-vinyl benzyl-g-dimethyl amino ethyl methacrylate) brush type graft copolymers via RAFT polymerization
Journal of Polymer Research (2015)