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Caesium chemistry

Beyond state I

Although caesium is well known in its oxidation state +I, many chemists have speculated about a possible higher state. Such a species has not yet been prepared, but based on quantum-chemical calculations CsFn compounds have now been predicted to be stable.

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References

  1. Wang, X., Andrews, L., Riedel, S. & Kaupp, M. Angew. Chem. Int. Ed. 46, 8371–8375 (2007).

    Article  CAS  Google Scholar 

  2. Gong, Y., Zhou, M., Kaupp, M. & Riedel, S. Angew. Chem. Int. Ed. 48, 7879–7883 (2009).

    Article  CAS  Google Scholar 

  3. Miao, M.-S. Nature Chem. 5, 846–852 10.1038/nchem.1754(2013).

    Article  CAS  Google Scholar 

  4. Pyykkö, P. Chem. Rev. 88, 563–594 (1988).

    Article  Google Scholar 

  5. Grochala, W., Hoffmann, R., Feng, J. & Ashcroft, N. W. Angew. Chem. Int. Ed. 46, 3620–3642 (2007).

    Article  CAS  Google Scholar 

  6. McMahon, J. M., Morales, M. A., Pierleoni, C. &. Ceperley, D. M. Rev. Mod. Phys. 84, 1607–1653 (2012).

    Article  CAS  Google Scholar 

  7. Guillaume, C. L. et al. Nature Phys. 7, 211–214 (2011).

    Article  CAS  Google Scholar 

  8. Struzhkin, V. V. et al. Nature 390, 382–383 (1997).

    Article  Google Scholar 

  9. Kurzydłowskia, D. & Grochala, W. Chem. Commun. 1073–1075 (2008).

  10. Riedel, S., Köchner, T., Wang, X. & Andrews, L. Inorg. Chem. 49, 7156–7164 (2010).

    Article  CAS  Google Scholar 

  11. Ault, B. S. & Andrews, L. J. Am. Chem. Soc. 98, 1591–1593 (1976).

    Article  CAS  Google Scholar 

  12. Takemura, K., Minomura, S. & Shimomura, O. Phys. Rev. Lett. 49, 1772–1775 (1982).

    Article  CAS  Google Scholar 

  13. Huber, K. P. & Herzberg, G. Molecular Spectra and Molecular Structure 4: Constants of Diatomic Molecules (Van Nostrand, 1979).

    Book  Google Scholar 

  14. Shannon, R. D. Acta Cryst. A32, 751–767 (1976).

    Article  CAS  Google Scholar 

Download references

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Correspondence to Sebastian Riedel or Peter Schwerdtfeger.

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Riedel, S., Schwerdtfeger, P. Beyond state I. Nature Chem 5, 815–816 (2013). https://doi.org/10.1038/nchem.1767

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