A simple aldehyde has been shown to catalyse an intermolecular hydroamination, not by activating either reaction partner, but simply by bringing them into close proximity.
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Tan, K. Temporary intramolecularity. Nature Chem 4, 253–254 (2012). https://doi.org/10.1038/nchem.1308
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DOI: https://doi.org/10.1038/nchem.1308
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