Compound 1f

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InChIKey AKGIMGIKRFMAOX-JCJYRYBFSA-N

Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.

A typical experimental procedure is given for compound 1a. Isolated yield 1.8 g, 95%. ¹H NMR (400.1 MHz, CD₂Cl₂, 30 °C): δ 7.47-7.28 (m, 10H, ArH), 2.56 (m, 2H, alkyl-CH), 2.28 (m, 2H, alkyl-CH), 1.97 (bd, 3H, AdH), 1.78 (d, 6H, AdH), 1.65 (q, 6H, AdH); ¹³C{¹H} NMR (100.6 MHz, CD₂Cl₂, 30 °C): δ 138.9 (d, ArC, J_C-P= 14 Hz), 133.3 (d, ArC, J_C-P= 19 Hz), 129.3 (s, ArC), 129.0 (s, ArC, J_C-P= 7 Hz), 45.3 (s, CSAd), 44.2 (s, CH₂Ad), 36.9 (s, CH₂Ad), 30.5 (s, CHAd), 30.0 (d, AliphC, J_C-P= 14 Hz), 22.8 (d, AliphC, J_C-P= 22 Hz); ³¹P {¹H} NMR (162.0 MHz, CD₂Cl₂, 30 °C): δ - 16.3 (s). Calculated for C₂₄H₂₉PS: C, 75.75; H, 7.68; found: C, 75.61; H, 7.74.