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Implementing a chemical C–N coupling step to intercept reactive intermediates in electrocatalytic CO2 or NOxy– reduction reactions is an emerging approach to sustainable electrosynthesis of organonitrogen compounds from cheap and abundant feedstocks.
The electrochemical construction of C–N bonds from abundant CO2 and nitrogenous sources is of interest for the sustainable synthesis of value-added organonitrogen compounds, which requires comprehensive considerations of electrocatalysts, the interface microenvironment, mechanisms, reactors and paired reactions to push this area towards competition with traditional thermochemical methods.
Irreproducible synthetic methods consume time, money, and resources. Here, we highlight the steps Nature Synthesis takes to help authors make their synthetic procedures as reproducible as possible.
Metal–organic frameworks are important catalysts for photocatalytic CO2 reduction but if the field is to continue to advance, then reporting of photocatalytic metrics and practices must be standardized.
Francesca Paradisi, Professor of Sustainable Pharmaceutical Chemistry at the University of Bern, talks to Nature Synthesis about the reactivity of biocatalysts in flow.