Abstract
A highly gas permeable polymer, poly(1-trimethylsilyl-1-propyne) (poly(TMSP)), was applied as a matrix of the optical oxygen sensor using the oxygen-induced luminescence quenching of octaethylporphyrin (OEP) platinum (PtOEP) or palladium complex (PdOEP). OEP complex was homogeneously dispersed in poly(TMSP) to give a mechanical tough film with thickness of 10µm. The luminescence intensity of OEP complex dispersed in the poly(TMSP) films drastically decreased with an increase in oxygen concentration. The oxygen sensitivity of the film (I0/I100) was very high and estimated to be 225 for PtOEP and 121 for PdOEP, respectively. The Stern–Volmer constants of PtOEP and PdOEP dispersed in poly(TMSP) films are estimated to be 6.6 and 17%-1, respectively. These results indicate that OEP metal complex dispersed in the poly(TMSP) films are novel optical sensing material for trace analysis of oxygen.
Similar content being viewed by others
Article PDF
References
C. Prininger, I. Klimant, and O. S. Wolfbeis, Anal. Chem., 66, 1841 (1994).
R. C. Martin, S. F. Malin, D. J. Bartnil, A. M. Schilling, and S. C. Furlong, Proc. SPIE., 2131, 426 (1994).
M. J. Atkinson, F. I. M. Thomas, N. Larson, E. Terrill, K. Morita, and C. C. Lium, Deep-Sea Res. I., 42, 761 (1995).
D. A. Skoog, D. M. West, and F. J. Holler, “Fundamentals of Analytical Chemistry”, Saunders, Philadelphia, PA, 1988, p 344.
L. C. Clark, Trans. Am. Soc. Artif. Intern. Organs, 2, 41 (1956).
T. M. Freeman and W. R. Seitz, Anal. Chem., 53, 98 (1981).
H. D. Hendricks, U. S. Patent 3 709 663 (Jan. 9, 1973).
Y. Suzuki, H. Nishide, and E. Tsuchida, Macromolecules, 33, 2530 (2000).
T. Ishiji and M. Kaneko, Analyst, 120, 1633 (1995).
A. Sharma and O. S. Wolfbeis, Appl. Spect., 42, 1009 (1988).
E. D. Lee, T. C. Werner, and R. Seitz, Anal. Chem., 59, 279 (1987).
S. M. Ramasamy and R. J. Hurubise, Anal. Chim. Acta, 152, 83 (1983).
H. W. Kroneis and H. J. Marsoner, Sens. Actuators, 4, 587 (1983).
W. Xu, R. Schmidt, M. Whaley, J. N. Demas, B. A. DeGraff, E. K. Karikari, and B. L. Farmer, Anal. Chem., 67, 3172 (1995).
J. Olmsted, Chem. Phys. Lett., 26, 33 (1974).
P. Hartmann, M. J. P. Leiner, and M. E. Lippitsch, Anal. Chem., 67, 88 (1995).
M. G. Sasso, F. H. Quina, and E. J. H. Bechera, Anal. Biochem., 156, 239 (1986).
E. Singer, G. L. Duveneck, M. Ehrat, and M. Widmer, Sens. Actuators, A, 41, 542 (1994).
E. R. Carraway, J. N. Demas, B. A. DeGraff, and J. R. Bacon, Anal. Chem., 63, 332 (1991).
J. R. Bacon and J. N. Demas, Anal. Chem., 59, 2780 (1987).
X. M. Li and H. Y. Wong, Anal. Chim. Acta, 262, 27 (1992).
W. Y. Xu, K. A. Kneas, J. N. Demas, and B. A. DeGraff, Anal. Chem., 68, 2605 (1996).
L. Sacksteder, J. N. Demas, and B. A. DeGraff, Anal. Chem., 65, 3480 (1993).
D. B. Papkovsky, G. V. Ponomarev, W. Trettnak, and P. O’Leary, Anal. Chem., 67, 4112 (1995).
J. Vanderkooi, G. Maniara, J. Green, and D. F. Wilson, J. Biol. Chem., 262, 5476 (1987).
Mills and A. Lepre, Anal. Chem., 69, 4653 (1997).
K. Kalyanasundaram, “Photochemistry of Polypyridine and Porphyrin Complexes”, Academic Press, Inc., New York, N.Y., 1992, p 500.
S-K. Lee and I. Okura, Anal. Sci., 13, 535 (1997).
S-K. Lee and I. Okura, Spectrochim. Acta, Part A, 54, 91 (1998).
S. Pauly, “Polymer Handbook, 3rd ed.”, John Wiley & Sons, Inc., New York, N.Y., 1989.
T. Masuda, E. Isobe, T. Higashimura, and K. Takada, J. Am. Chem. Soc., 105, 7473 (1983).
B. D. MacCraith, C. M. McDonagh, G. O’Keeffe, E. T. Keyes, J. G. Vos, B. O’Kelly, and J. F. McGilp, Analyst, 118, 385 (1993).
J. N. Demas, B. A. DeGraff, and W. Xu, Anal. Chem., 67, 1377 (1995).
T. Masuda, E. Isobe, and T. Higashimura, Macromolecules, 18, 841 (1985).
K. Takada, H. Matsuya, T. Masuda, and T. Higashimura, J. Appl. Polym. Sci., 30, 1605 (1985).
T. Masuda, Y. Iguchi, B-Z. Tang, and T. Higashimura, Polymer, 29, 2041 (1988).
Y. Ichiraku, S. A. Stern, and T. Nakagawa, J. Membr. Sci., 34, 5 (1987).
H. Nishide, H. Kawakami, Y. Sasame, K. Ishikawa, and E. Tsuchida, J. Polym. Sci., Part A: Polym. Chem., 30, 77 (1992).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Amao, Y., Okura, I., Shinohara, H. et al. An Optical Sensing Material for Trace Analysis of Oxygen. Metalloporphyrin Dispersed in Poly(1-trimethylsilyl-1-propyne) Film. Polym J 34, 411–417 (2002). https://doi.org/10.1295/polymj.34.411
Issue Date:
DOI: https://doi.org/10.1295/polymj.34.411