Photovoltaics is expected to provide the next generation of safe, secure, sustainable and affordable energy. The challenges now are to reduce costs and improve power-conversion efficiencies. This Focus Issue covers cutting-edge solar cell technologies such as polymer, dye-sensitized and intermediate-band solar cells, as well as advanced light-harvesting techniques based on plasmonics and quantum dots. Also included is an interview with the world's largest solar-cell manufacturer on the future of the photovoltaic industry.