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Volume 8 Issue 9, September 2013

The chemistry of molecules that form a self-assembled monolayer depends on the curvature of the surface onto which they are tethered. Bartosz Grzybowski and colleagues coat dumbbell-shaped nanoparticles (yellow in the artistic representation on the cover) with a monolayer of 1-mercaptoundecanoid acid (red) and observe that the acidic properties of the molecule depend on where it is attached on the nanoparticle. The researchers take advantage of this effect and induce the dumbbell-shaped nanoparticles to self-assemble in different ways by changing the pH of the solution.

Article p676; News & Views p620

IMAGE: DAVID A. WALKER

COVER DESIGN: ALEX WING

Editorial

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Commentary

  • In recent years, there has been a proliferation of models for spin-dependent electronic processes in organic semiconductors. Researchers aiming to utilize these processes for new organic spintronics devices should focus more on scrutinizing these models experimentally by embracing spectroscopy.

    • Christoph Boehme
    • John M. Lupton
    Commentary
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Research Highlights

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News & Views

  • Extremely sensitive and ultrasmall superconducting quantum interference devices can be fabricated on sharp nanoscale tips.

    • Dieter Koelle
    News & Views
  • A combination of self-assembly and jet printing can be used to create block copolymer films with complex structures and tunable periodicities across a large substrate.

    • Richard A. Register
    News & Views
  • The local curvature of dumbbell-shaped nanoparticles can be used to control the ionization state of a molecular layer adsorbed on their surfaces and the self-assembly patterns of the particles.

    • Orlin D. Velev
    News & Views
  • The conductance of an electronic nanodevice can be switched by an applied current between two well-defined values, which correspond to atomic configurations that differ as a result of the rearrangement of a single atom.

    • Sense Jan van der Molen
    News & Views
  • Condensed-matter physicists are steadily closing in on exotic excitations known as Majorana modes that could advance both fundamental science and quantum computing.

    • Jason Alicea
    News & Views
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Review Article

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Letter

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Article

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