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The chemistry of molecules that form a self-assembled monolayer depends on the curvature of the surface onto which they are tethered. Bartosz Grzybowski and colleagues coat dumbbell-shaped nanoparticles (yellow in the artistic representation on the cover) with a monolayer of 1-mercaptoundecanoid acid (red) and observe that the acidic properties of the molecule depend on where it is attached on the nanoparticle. The researchers take advantage of this effect and induce the dumbbell-shaped nanoparticles to self-assemble in different ways by changing the pH of the solution.
In recent years, there has been a proliferation of models for spin-dependent electronic processes in organic semiconductors. Researchers aiming to utilize these processes for new organic spintronics devices should focus more on scrutinizing these models experimentally by embracing spectroscopy.
A combination of self-assembly and jet printing can be used to create block copolymer films with complex structures and tunable periodicities across a large substrate.
The local curvature of dumbbell-shaped nanoparticles can be used to control the ionization state of a molecular layer adsorbed on their surfaces and the self-assembly patterns of the particles.
The conductance of an electronic nanodevice can be switched by an applied current between two well-defined values, which correspond to atomic configurations that differ as a result of the rearrangement of a single atom.
Condensed-matter physicists are steadily closing in on exotic excitations known as Majorana modes that could advance both fundamental science and quantum computing.
Excitonic valley quantum coherence is optically generated and detected by polarization-resolved photoluminescence spectroscopy in the monolayer semiconductor WSe2.
Nanoscale superconducting quantum interference devices (SQUIDs) fabricated on the apex of a sharp tip can provide spin sensitivities that are nearly two orders of magnitude better than previous SQUID sensors.
Electromigration is used to rearrange single atoms in an atomic-sized metal contact and to switch its conductance between two well-defined values, enabling memory device functionality.
Three-dimensional films — comprising polymeric phases of different molecular weights and compositions — are arranged in complex hierarchical patterns and used for wafer-scale patterning.
The chemical properties of a molecular monolayer on the surface of a non-spherical nanoparticle depend on its local curvature; an effect that can be exploited to drive the self-assembly of these nanoparticles into different structures.