Empty liquids and equilibrium gels have so far been only theoretical possibilities, predicted for colloids with patchy interactions. But evidence of both has now been found in Laponite, a widely studied clay.
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Kegel, W., Lekkerkerker, H. Clay goes patchy. Nature Mater 10, 5–6 (2011). https://doi.org/10.1038/nmat2927
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DOI: https://doi.org/10.1038/nmat2927
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