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Nature 429, 822 (24 June 2004) | doi:10.1038/429822a

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Metrology:  Electrifying effects in colloids

Patrick Warren1

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The electric field generated in the sedimentation or centrifugation of charged colloidal particles could be exploited to determine the charge and the mass of macromolecules in a single experiment.

It might be thought that the last word on sedimentation or centrifugation had been said long ago. But over the past decade there have been persistent indications from experiment1, theory2 and simulations3 of an unusual phenomenon in the sedimentation equilibrium of suspensions of charged colloidal particles when the ionic strength is low.

  1. Patrick Warren is at Unilever R&D Port Sunlight, Bebington, Wirral CH63 3JW, UK.
    e-mail: Email: patrick.warren@unilever.com

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