Abstract
Effects of substituted side-chains of poly(2,5-dialkoxy-1,4-phenylenevinylene) derivatives (PPV) on polymer orientation have been studied using polarized optical spectroscopy and synchrotron-sourced grazing incidence X-ray diffraction (GIXD) analysis. The results of polarized optical spectroscopy indicate that the symmetrically substituted PPV is suitable for homogeneous oriented film preparation by friction-transfer technique. The formed film of poly(2,5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (BEHPPV) exhibited large light emission dichroism of up to 42.0. The results of synchrotron-sourced GIXD for BEHPPV film indicated that the BEHPPV molecules crystallized in not a different manner from that of other PPV.
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Nagamatsu, S., Misaki, M., Kimura, T. et al. Side-Chain Effects on Friction-Transferred Polymer Orientation. Polym J 39, 1300–1305 (2007). https://doi.org/10.1295/polymj.PJ2007062
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DOI: https://doi.org/10.1295/polymj.PJ2007062
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