Abstract
Molybdenum(IV, V) thiolate and selenolate complex with four long bundling hydrocarbon chains connected to the amide group, (Ph4P)[MoVO{S-2-CH3(CH2)10CONHC6H4}4] and (NEt4)2[MoIVO{Se-2-CH3(CH2)10CONHC6H4}4] were synthesized. The four chains are oriented toward the same direction in the solution as established by 1H NMR. These complexes were soluble in an aqueous micellar solution and stabilized against hydrolysis in such aqueous media efficiently by the hydrocarbon chains. The preliminary results of X-ray analysis revealed the individual molecular assembly behavior which depends significantly on the oxidation state of metal ion and the kind of coordinated atom.
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Okamura, Ta., Taniuchi, K., Ueyama, N. et al. Molecular Assembly and Micellization of Molybdenum(V, IV) Thiolate and Selenolate Complexes with Long Hydrocarbon Chains. Polym J 31, 651–657 (1999). https://doi.org/10.1295/polymj.31.651
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DOI: https://doi.org/10.1295/polymj.31.651