Compound 2f

cis-Dichloro-(((2-((3s,5s,7s)-adamantan-1-ylthio)ethyl)diphenylphosphine-κ2P,S) platinum(II)

From: A coordination chemistry dichotomy for icosahedral carborane-based ligands

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InChIKey AYIKVXFOIKLXTN-UXIIVFRPSA-L

Compound data: CIF

Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.

A typical experimental procedure is given for compound 2a. 1H NMR (400.1 MHz, CD2Cl2, 30 °C): δ 8.00-7.11 (m, 10H, ArH), 3.01-2.33 (bm, 4H, alkyl-CH), 2.27-2.14 (bs, 3H, AdH), 2.13-1.83 (bs, 6H, AdH), 1.64 (bs, 6H, AdH); 31P {1H} NMR (162.0 MHz, CD2Cl2, 30 °C): δ 40.7 (s, JP-Pt= 3608 Hz). HRMS (ESI): m/z calcd for C24H29ClPPtS [M-Cl]+: 610.1064, found: 610.1050. Single crystals of X-Ray quality were grown by slow evaporation from dichloromethane in a NMR tube.