Compound 2e
cis-Dichloro-(((2-(t-butylthio)ethyl)diphenylphosphine)-κ2P,S) platinum(II)
From: A coordination chemistry dichotomy for icosahedral carborane-based ligands
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InChIKey GXJJLKMNLFMNOY-UHFFFAOYSA-L
Synthetic procedure: See article for the definitive version of this procedure and for full experimental details.
A typical experimental procedure is given for compound 2a. 1H NMR (400.1 MHz, CD2Cl2, 30 °C): δ 8.02-7.85 (m, 2H, ArH), 7.72-7.21 (m, 8H, ArH), 2.98-2.23 (m, 4H, alkyl-CH), 1.47 (s, 9H, CH); 31P {1H} NMR (100.6 MHz, CD2Cl2, 30 °C): δ 40.1 (s, JP-Pt= 3600 Hz). HRMS (ESI): m/z calcd for C18H23ClPPtS [M-Cl]+: 532.0594, found: 532.0547.
