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Evidence for a 50% increase in H202 over the past 200 years from a Greenland ice core

Abstract

HYDROGEN peroxide has attracted increasing attention from atmospheric chemists over the past decade, because in the gas phase it acts as a reservoir species of OH radicals1,2, and in the aqueous phase it plays a key role in the oxidation of SO2 to H2SO4 in clouds3. It is also known to have an adverse effect on trees and plants4. In 1984, hydrogen peroxide was identified as one of the dominant trace species in polar ice5, introducing the possibility of constructing a record of atmospheric hydrogen peroxide concentrations from ice-core data. Here we present such a record for the past 700 years from Summit, Central Greenland. We find that hydrogen peroxide concentrations have increased by 50% over the past 200 years, with most of the increase occurring in the past 20 years, indicating that human activities may be responsible for such a dramatic change.

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References

  1. Logan, J. A., Prather, M. J., Wofsy, S. C. & McElroy, M. B. J. geophys. Res. 86, 7210–7254 (1981).

    Article  ADS  CAS  Google Scholar 

  2. Kleinman, L. I. J. geophys. Res. 91, 10889–10904 (1986).

    Article  ADS  CAS  Google Scholar 

  3. Penkett, S. A., Jones, B. M., Brice, K. A. & Eggleton, A. E. Atmos. Envir. 13, 123–137 (1979).

    Article  CAS  Google Scholar 

  4. Möller, D. Atmos. Envir. 23, 1625–1627 (1989).

    Article  Google Scholar 

  5. Neftel, A., Jacob, P. & Klockow, D. Nature 311, 43–45 (1984).

    Article  ADS  CAS  Google Scholar 

  6. Lazrus, A. L., Kok, G. L., Gitlin, S. N., Lind, J. A. & McLaren, S. E. Analyt. Chem. 57, 917–922 (1985).

    Article  CAS  Google Scholar 

  7. Hwang, H. & Dasgupta, P. K. Analytics chim. Acta 170, 347–352 (1985).

    Article  CAS  Google Scholar 

  8. Dasgupta, P. K. & Hwang, H. Analyt. Chem. 57, 1009–1012 (1985).

    Article  CAS  Google Scholar 

  9. Sigg, A. & Neftel, A. Ann. Glaciol. 10, 157–162 (1988).

    Article  ADS  CAS  Google Scholar 

  10. Johnsen, S. J. Int. Ass. Hydrol. Sci. Publ. No. 118, 210–219 (Grenoble, 1977).

  11. Herron, M. M. & Langway, C. C. J. Glaciol. 25, 373–385 (1980).

    Article  ADS  Google Scholar 

  12. Laj, P., Drummey, S. M., Spencer, M. J., Palais, J. M. & Sigurdsson, H. Nature 346, 45–48 (1990).

    Article  ADS  CAS  Google Scholar 

  13. Thompson, A. M., Owens, M. A. & Stewart, R. W. Geophys. Res. Lett. 16, 53–56 (1989).

    Article  ADS  CAS  Google Scholar 

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Sigg, A., Neftel, A. Evidence for a 50% increase in H202 over the past 200 years from a Greenland ice core. Nature 351, 557–559 (1991). https://doi.org/10.1038/351557a0

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