Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Article
  • Published:

Nebular condensation of Ga, Ge and Sb and the chemical classification of iron meteorites

Abstract

Key parameters for classifying iron meteorites into genetic groups are concentrations of Ga and Ge. Their taxonomic value results from the combination of very wide concentration ranges in iron meteorites as a whole, with very narrow concentration ranges in most individual groups. The very wide intergroup ranges result from solar nebular condensation in widely varying conditions. Recent calculations show that the nebular condensation temperature of Ge is lower than that of any other siderophile, and that Sb and Ga are the next most volatile siderophiles. The narrow intragroup ranges of Ga and Ge reflect minimal fractionation during the crystallisation of cores, larger intragroup ranges for Sb result from a solid/liquid distribution ratio near 0.4.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Wasson, J. T. Geochim. cosmochim. Acta 31, 161–180 (1967).

    Article  ADS  CAS  Google Scholar 

  2. Scott, E. R. D., Wasson, J. T. & Buchwald, V. F. Geochim. cosmochim. Acta 37, 1957–1983 (1973).

    Article  ADS  CAS  Google Scholar 

  3. Scott, E. R. D. & Wasson, J. T. Geochim. cosmochim. Acta 40, 103–115 (1976).

    Article  ADS  CAS  Google Scholar 

  4. Goldberg, E., Uchiyama, A. & Brown, H. Geochim. cosmochim. Acta 2, 1–25 (1951).

    Article  ADS  CAS  Google Scholar 

  5. Lovering, J. F., Nichiporuk, W., Chodos, A. & Brown, H. Geochim. cosmochim. Acta 11, 263–278 (1957).

    Article  ADS  CAS  Google Scholar 

  6. Wasson, J. T. Meteorites—Classification and Properties (Springer, Berlin, 1974).

    Google Scholar 

  7. Buchwald, V. F. Handbook of iron Meteorites (University of California Press, 1975).

    Google Scholar 

  8. Scott, E. R. D. & Wasson, J. T. Rev. geophys. Space Phys. 13, 527–546 (1975).

    Article  ADS  CAS  Google Scholar 

  9. Wasson, J. T. Icarus 12, 407–423 (1970).

    Article  ADS  CAS  Google Scholar 

  10. Scott, E. R. D. & Bild, R. W. Geochim. cosmochim. Acta 38, 1379–1391 (1974).

    Article  ADS  CAS  Google Scholar 

  11. Kelly, W. R. & Larimer, J. W. Geochim. cosmochim. Acta 41, 93–111 (1977).

    Article  ADS  CAS  Google Scholar 

  12. Scott, E. R. D. Geochim. cosmochim. Acta 36, 1205–1236 (1972).

    Article  ADS  CAS  Google Scholar 

  13. Wasson, J. T. Proc. 24th Int. Geol. Congr. 15, 161–168 (1972).

    CAS  Google Scholar 

  14. Anders, E. Space Sci. Rev. 3, 583–714 (1964).

    Article  ADS  CAS  Google Scholar 

  15. Larimer, J. W. & Anders, E. Geochim. comochim. Acta 31, 1269–1270 (1967).

    ADS  Google Scholar 

  16. Wai, C. M., Wetherill, G. W. & Wasson, J. T. Geochim. cosmochim. Acta 32, 1269–1278 (1968).

    Article  ADS  Google Scholar 

  17. Wasson, J. T. & Wai, C. M. Nature 261, 114–116 (1976).

    Article  ADS  CAS  Google Scholar 

  18. Scott, E. R. D. Geochim. cosmochim. Acta 42, 1447–1458 (1978).

    Article  ADS  CAS  Google Scholar 

  19. Willis, J. & Wasson, J. T. (in preparation).

  20. Wai, C. M. & Wasson, J. T. Earth planet. Sci. Lett. 36, 1–13 (1977).

    Article  ADS  CAS  Google Scholar 

  21. Modell, M. & Reid, R. C. Thermodynamics and Its Applications (Prentice-Hall, Englewood Cliffs, 1974).

    Google Scholar 

  22. Hultgren, R., Desai, P. D., Hawkins, D. T., Gleiser, M. & Kelley, K. K. Selected Values of the Thermodynamic Properties of Binary Alloys (Am. Soc. Met., Metal Park, Ohio, 1973).

    Google Scholar 

  23. Tanutrov, I. N., Vatolin, N. A., Okunev, A. I. & Esin, O. A. Zh. Fiz. Khim. 42, 2805–2807 (1968).

    CAS  Google Scholar 

  24. Ivanova, V. D. & Burylev, B. P. Zh. Fiz. Khim. 45, 2056–2057 (1971).

    CAS  Google Scholar 

  25. Vaisburd, S. E. & Remen, T. F. Zh. Fiz. Khim. 42, 745–747 (1968).

    CAS  Google Scholar 

  26. Predel, B. & Vogelbein, W. Thermochim. Acta 13, 133–145 (1975).

    Article  CAS  Google Scholar 

  27. Predel, B., Vogelbein, W. & Schallner, U. Thermochim. Acta 12, 367–375 (1975).

    Article  CAS  Google Scholar 

  28. Dynan, J. & Miller, E. J. chem. Thermodyn. 7, 1163–1172 (1975).

    Article  CAS  Google Scholar 

  29. Takahashi, H., Janssens, M. J., Morgan, J. W. & Anders, E. Geochim. cosmochim. Acta 42, 97–106 (1978).

    Article  ADS  CAS  Google Scholar 

  30. Zemann, J. Kristallchemie (de Gruyter, Berlin, 1966).

    Google Scholar 

  31. Battat, D., Faktor, M. M. & Moss, R. H. JCS, Faraday I. 70, 2280–2292 (1974).

    Article  CAS  Google Scholar 

  32. Sears, D. Earth planet. Sci. Lett. 41, 128–138 (1978).

    Article  ADS  CAS  Google Scholar 

  33. Mason, B. Handbook of Elemental Abundances in Meteorites (Gordon and Breech, New York, 1971).

    Google Scholar 

  34. Dreibus, G., Spettel, B. & Wänke, H. J. radioanalyt. Chem. 38, 391–403 (1977).

    Article  ADS  CAS  Google Scholar 

  35. Fegley, B. & Lewis, J. Icarus 38, 166–179 (1979).

    Article  ADS  CAS  Google Scholar 

  36. Cameron, A. G. W. Space Sci. Rev. 15, 121–146 (1973).

    Article  ADS  CAS  Google Scholar 

  37. Kelley, K. K. Bull. U.S. Bur. Mines. 584 (1960).

  38. Wagman, D. D. et al. NBS Tech. Not. 270–273 (1968).

  39. Mills, K. C. Thermodynamic Data for Inorganic Sulphides, Selenides, and Tellurides (Butterworth, London, 1974).

    Google Scholar 

  40. Faure, F. M., Mitchell, M. J. & Bartlett, R. W. High Temp. Sci. 4, 181–191 (1972).

    CAS  Google Scholar 

  41. Smales, A. A., Mapper, D. & Fouché, K. F. Geochim. cosmochim. Acta 31, 673–720 (1967).

    Article  ADS  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wai, C., Wasson, J. Nebular condensation of Ga, Ge and Sb and the chemical classification of iron meteorites. Nature 282, 790–793 (1979). https://doi.org/10.1038/282790a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/282790a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing