The chemistry of the atmosphere was a largely neglected topic until the last decade during which concern about pollution has produced a flurry of activity. The processes which may deplete the relatively small amount of ozone in the stratosphere which protects us from harmful UV light have much in common with those in the Los Angeles-type smog which generate ozone and other oxidants. Such systems involve chain reactions in which free radicals such as HO, HO2, ClO can carry out a chemical conversion process (ozone to oxygen) many times before they are destroyed. Recent research shows that nitrogen oxides from the exhausts of supersonic aircraft or derived from increased use of nitrogenous fertilisers will have little effect on stratospheric ozone but the potential effects of chlorine compounds, such as aerosol propellants, require careful examination. In contrast, the oxidation of carbon monoxide is now thought to be a major source of ozone in the lower atmosphere.
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Thrush, B. Recent developments in atmospheric chemistry. Nature 276, 345–348 (1978). https://doi.org/10.1038/276345a0
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DOI: https://doi.org/10.1038/276345a0
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