Abstract
HYDROXYL groups have been proposed as catalytic agents for reactions involving molecules sorbed in dehydrated zeolites1, and there has been extensive infrared study of them (see refs. 2 and 3 for summaries). Speculations have been made on the positions of the hydroxyl groups in faujasite, Y and X zeolites on the basis of the band frequencies, and on the frequency changes induced by molecular sorption and by deuterium and cation exchange. But most discussions have been rather general and have not considered the detailed properties of the crystal structure.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on SpringerLink
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Mays, R. L., and Pickert, P. E., Conf. on Molecular Sieves, London (1967).
Angell, C. L., and Schaffer, P. C., J. Phys. Chem., 69, 3463 (1965).
Basila, M. R., Appl. Spectros. Rev., 1 (2), 289 (1968).
Uytterhoeven, J. B., Christner, L. G., and Hall, W. K., J. Phys. Chem., 69, 2117 (1965).
Bragg, W. L., and Claringbull, G. F., Crystal Structures of Minerals (Cornell University Press, Ithaca, NY, 1965).
Smith, J. V., Bennett, J. M., and Flanigen, E. M., Nature, 215, 241 (1967).
Olson, D. H., Kokotailo, G. T., and Charnell, J. F., Nature, 215, 270 (1967).
Olson, D. H., Kokotailo, G. T., and Charnell, J. F., 41st National Colloid Symp., Buffalo, New York (1967).
Eulenberger, G. R., Shoemaker, D. P., and Keil, J. G., J. Phys. Chem., 71, 1812 (1967).
Rabo, J. A., Angell, C. L., and Schomaker, V., Fourth Intern. Congr. Catalysis, Moscow (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SMITH, J., BENNETT, J. Hydroxyl Groups in Zeolite Catalysts. Nature 219, 1040–1041 (1968). https://doi.org/10.1038/2191040a0
Received:
Issue Date:
DOI: https://doi.org/10.1038/2191040a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.