Abstract
THE unstable blue compounds obtained by the reduction of tungstic oxide with active hydrogen were classified as “bronzes” by Glemser1,2 and shown by X-ray powder photography to exhibit structural variations with composition similar to those observed for the alkali-metal tungsten bronzes. In this note we report a new tetragonal hydrogen bronze phase with the same crystal structure as Na(0.1)WO3 (ref. 3), and with 0.21<x<0.25.
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References
Glemser, O., and Naumann, C., Z. Anorg. Chem., 265, 289 (1951).
Glemser, O., and Lutz, G., Z. Anorg. Chem., 263, 17 (1951).
Magneli, A., Acta Chem. Scand., 5, 670 (1951).
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DICKENS, P., HURDITCH, R. X-ray and Neutron Diffraction Studies of a Tetragonal Hydrogen Bronze HxWO3. Nature 215, 1266–1267 (1967). https://doi.org/10.1038/2151266a0
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DOI: https://doi.org/10.1038/2151266a0
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