Abstract
IN previous publications the electron spin resonance data of dithiocarbamates of the coinage metals ([RR′NCS2]2Me ; Me = copper, silver or gold) have been used for a determination of valence states of the metals1 and in a discussion of the bonding of the metal ions2. The copper and silver compounds exhibit very low effective spin-orbit coupling energy with small resonance anisotropy and unusually narrow linos. The small line-width makes it possible to analyse the influence on the width from a number of factors, and we shall briefly report on the effect of temperature, of dissolved oxygen and of different solvents.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Vänngård, T., and Åkerström, S., Nature, 184, 183 (1959).
Pettersson, R., and Vänngård, T., Arkiv Kemi, 17, 249 (1961).
McConnell, H. M., J. Chem. Phys., 25, 709 (1956).
Kivelson, D., J. Chem. Phys., 33, 1094 (1960).
Rogers, R. N., and Pake, G. E., J. Chem. Phys., 33, 1107 (1960).
International Critical Tables VII 214 (McGraw-Hill, New York and London, 1930).
Pake, G. E., and Tuttle, jun., T. R., Phys. Rev. Letters, 3, 423 (1959).
Al'tshuler, S. A., and Valiev, K. A., Soviet Phys. JETP, 35, 661 (1959).
Fischer, F., and Pfleiderer, G., Z. anorg. u. allgem. Chem., 124, 61 (1922).
Bloembergen, N., Purcell, E. M., and Pound, R. V., Phys. Rev., 73, 679 (1948).
Pake, G. E., and Sands, R. H., Phys. Rev., 98, 266 (1955).
McGarvey, B. R., J. Phys. Chem., 60, 71 (1956).
Krebs, H., Weber, E. F., and Fassbender, H., Z. anorg. Chem., 276, 128 (1954).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
AASA, R., PETTERSSON, R. & VÄNNGÅRD, T. Electron Spin Resonance Line-Widths in Solutions of Copper and Silver Dithiocarbamates. Nature 190, 258–259 (1961). https://doi.org/10.1038/190258a0
Issue Date:
DOI: https://doi.org/10.1038/190258a0
This article is cited by
-
The study of the reaction of bis-chelate compounds of copper(II) with electron-donor bases by ESR and NMR methods
Journal of Structural Chemistry (1976)
-
Symmetrie und Mikrowellenspektren mehratomiger paramagnetischer Zentren
Physik der Kondensierten Materie (1963)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
